{"id":"W2324161879","doi":"10.1021/om401129w","title":"Reactivity with Alkylaluminum of a Chromium Complex of a Pyridine-Containing PNP Ligand: Redox N–P Bond Cleavage","year":2014,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":24,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Chemistry; Phosphine; Medicinal chemistry; Ligand (biochemistry); Chromium; Adduct; Protonation; Isostructural; Bond cleavage; Metal; Stereochemistry; Pyridine; Redox; Toluene; Catalysis; Crystallography; Organic chemistry; Crystal structure","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000214746,0.0002730789,0.000166649,0.0001088219,0.0001273503,0.0003048422,0.0005276818,0.0003705423,0.0007756259],"category_scores_gemma":[0.0003510234,0.000125509,0.0001232766,0.0001385797,0.0002167789,0.0001729473,0.0002663052,0.0003115275,0.0002140649],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004550749,"about_ca_system_score_gemma":0.0001637863,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001300092,"about_ca_topic_score_gemma":0.001878004,"domain_scores_codex":[0.9997614,0.00004972567,0.0000106467,0.00004861641,0.00007355372,0.00005614054],"domain_scores_gemma":[0.9998968,0.00002073701,0.00002724711,0.00001814509,0.00001696772,0.00002016366],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001678163,0.00002042971,0.0001576789,0.00006571594,0.00001112427,0.00008317039,0.00006549744,0.0002387861,0.9977508,0.000164471,0.00003838569,0.001236037],"study_design_scores_gemma":[0.000008707417,0.0001497576,0.0003501153,0.000002154164,0.000006041872,0.00008418268,0.00001144928,0.00051815,0.99837,0.00001000592,0.0004855625,0.000003893644],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.996443,0.0003990063,0.00120242,0.00002333777,0.000006314159,0.00001194051,0.00004700555,0.0000416545,0.001825408],"genre_scores_gemma":[0.9981664,0.0001218441,0.0006906902,0.000009140956,0.000001516263,0.000004152229,0.0000597377,0.000009522239,0.0009369368],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001300092,"threshold_uncertainty_score":0.003301859,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01430391286776175,"score_gpt":0.2147925526957457,"score_spread":0.2004886398279839,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}