{"id":"W2324203530","doi":"10.1021/jo301240j","title":"Syntheses of Carbocyclic Analogues of α-<scp>d</scp>-Glucosamine, α-<scp>d</scp>-Mannose, α-<scp>d</scp>-Mannuronic Acid, β-<scp>l</scp>-Idosamine, and β-<scp>l</scp>-Gulose","year":2012,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Canadian Institutes of Health Research","keywords":"Chemistry; Cyclohexanone; Stereochemistry; Glucosamine; Mannose; D-Glucosamine; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001726845,0.0005708794,0.0003942408,0.0002621731,0.0002576281,0.0003338773,0.0004222973,0.000264881,0.001867513],"category_scores_gemma":[0.0002236706,0.0001712171,0.0002756145,0.0003861341,0.0002809664,0.0003758511,0.0003416842,0.0006636442,0.0005374487],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005092934,"about_ca_system_score_gemma":0.0006258917,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001508125,"about_ca_topic_score_gemma":0.002374937,"domain_scores_codex":[0.9998412,0.00001703968,0.00001785399,0.00003491184,0.00002978401,0.00005918447],"domain_scores_gemma":[0.9998745,0.000009553663,0.000027313,0.0000297298,0.0000176701,0.0000412353],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002757175,0.0001435343,0.0001719631,0.0002986455,0.00002215816,0.0006019521,0.0002068985,0.0009332304,0.9770285,0.002599512,0.0004577284,0.01726009],"study_design_scores_gemma":[0.00005114484,0.0005245358,0.0003880733,0.00001002849,0.00001934505,0.0003356985,0.00003716291,0.0004742847,0.9877993,0.0001621337,0.01017861,0.00001973608],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9444006,0.004701886,0.02453981,0.0002947765,0.0003254962,0.000326166,0.001045633,0.0003853922,0.02398029],"genre_scores_gemma":[0.9802547,0.003022401,0.01131757,0.00007041257,0.00002572358,0.00007417634,0.0005353882,0.00006496398,0.004634612],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001867513,"threshold_uncertainty_score":0.006247401,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01398986396209952,"score_gpt":0.2216006069397136,"score_spread":0.207610742977614,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}