{"id":"W2324384216","doi":"10.1524/zpch.2011.0133","title":"Transient anisotropy in degenerate systems: A semi-classical approach","year":2011,"lang":"en","type":"article","venue":"Zeitschrift für Physikalische Chemie","topic":"Spectroscopy and Quantum Chemical Studies","field":"Physics and Astronomy","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"Steacie Institute for Molecular Sciences","funders":"Deutsche Forschungsgemeinschaft; Basis Foundation; Alexander von Humboldt-Stiftung","keywords":"Degenerate energy levels; Anisotropy; Ansatz; Dephasing; Physics; Excited state; Transient (computer programming); Statistical physics; Quantum; Basis (linear algebra); Classical mechanics; Quantum mechanics; Computer science; Mathematics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001739753,0.0004511421,0.0006614988,0.00006191112,0.0001310733,0.00005394442,0.0003654263,0.0001225725,0.0002257633],"category_scores_gemma":[0.000008307416,0.000388379,0.0002411317,0.0003376466,0.0001524419,0.000212948,0.0001080987,0.0004890949,0.00005145052],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001926298,"about_ca_system_score_gemma":0.00005517161,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000592751,"about_ca_topic_score_gemma":0.000003536018,"domain_scores_codex":[0.9976883,0.00006783141,0.0005224745,0.000668972,0.000297887,0.0007545406],"domain_scores_gemma":[0.9991215,0.00005333944,0.000139708,0.0004166152,0.00006420028,0.0002045928],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002247953,0.002593441,0.01046722,0.0002221237,0.0004712411,0.00001661158,0.004306263,0.0001675286,0.6034339,0.3680218,0.00977105,0.0003040491],"study_design_scores_gemma":[0.001584258,0.00007799673,0.001166532,0.00008725229,0.00009029487,0.000003086252,0.001193493,0.0019734,0.9764035,0.0006430724,0.01598339,0.0007937552],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6663987,0.0007100502,0.005746974,0.00009008093,0.0002674233,0.000550082,0.0001449186,0.0001710562,0.3259207],"genre_scores_gemma":[0.9973388,0.00001469441,0.001235769,0.00005234564,0.0005788178,0.0002533981,0.0001286076,0.00005269662,0.0003448364],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.3729696,"threshold_uncertainty_score":0.9998568,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02740266494218199,"score_gpt":0.2557336937305237,"score_spread":0.2283310287883417,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}