{"id":"W2324423536","doi":"10.1021/es104362g","title":"Atmospheric Degradation of Perfluoro-2-methyl-3-pentanone: Photolysis, Hydrolysis and Hydration","year":2011,"lang":"en","type":"article","venue":"Environmental Science & Technology","topic":"Per- and polyfluoroalkyl substances research","field":"Environmental Science","cited_by":60,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Photodissociation; Hydrolysis; Radical; Yield (engineering); Degradation (telecommunications); Photochemistry; Atmospheric chemistry; Environmental chemistry; Ozone; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002067585,0.0003407653,0.0001840452,0.000146405,0.000155596,0.0001914645,0.0001315658,0.0003210405,0.001013368],"category_scores_gemma":[0.0001849605,0.0001146761,0.0002800102,0.0001631903,0.0001364401,0.0002986208,0.0001523654,0.0002640079,0.000268742],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003428507,"about_ca_system_score_gemma":0.0001847007,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.004720931,"about_ca_topic_score_gemma":0.003939806,"domain_scores_codex":[0.9998497,0.0000141778,0.000005562938,0.0000444397,0.00005198799,0.00003406394],"domain_scores_gemma":[0.9999382,0.00001133512,0.00001799469,0.000004602413,0.00002027632,0.000007516031],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008509165,0.00001095645,0.001899112,0.00007096146,0.000008437725,0.00005839982,0.00002730816,0.0002289791,0.9932005,0.0000522243,0.00005195277,0.004306145],"study_design_scores_gemma":[0.000005059538,0.000213607,0.01714313,0.000006804958,0.00001142197,0.0001777166,0.00004142063,0.001829073,0.9791504,0.00005555997,0.001357406,0.000008425727],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9887187,0.002598393,0.00563673,0.0000537477,0.00001569131,0.00006323612,0.0006412777,0.00004452858,0.002227589],"genre_scores_gemma":[0.9920575,0.001924371,0.003314331,0.00003971411,0.000008265847,0.00004478919,0.0004707731,0.00001293735,0.002127335],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004720931,"threshold_uncertainty_score":0.009386897,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009201874920551627,"score_gpt":0.2173657089453463,"score_spread":0.2081638340247947,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}