{"id":"W2324577158","doi":"10.1021/ol500129p","title":"Synthesis and Properties of Cholesteric Click-Phospholes","year":2014,"lang":"en","type":"article","venue":"Organic Letters","topic":"Synthesis and Properties of Aromatic Compounds","field":"Chemistry","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Foundation for Innovation","keywords":"Phosphole; Chemistry; Conjugated system; Linker; Supramolecular chemistry; Cholesteric liquid crystal; Stereochemistry; Combinatorial chemistry; Molecule; Organic chemistry; Polymer","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000245824,0.0002894,0.0001869137,0.0002699721,0.0001440736,0.0002991751,0.0001807482,0.0002954173,0.001708772],"category_scores_gemma":[0.0004621359,0.0001210696,0.0001280999,0.0001788541,0.0001251548,0.0003092631,0.0001966941,0.0002729225,0.0005056421],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002522428,"about_ca_system_score_gemma":0.0001472076,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003007362,"about_ca_topic_score_gemma":0.0004202402,"domain_scores_codex":[0.9998604,0.0000121841,0.00001850222,0.00002947598,0.0000525372,0.00002688202],"domain_scores_gemma":[0.9997522,0.0000439336,0.00007188367,0.00002157958,0.00006218622,0.00004818085],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004907009,0.00001158148,0.00009174488,0.00004117627,0.000003072578,0.00005225875,0.00001913723,0.000213685,0.9973213,0.00009542169,0.0000404365,0.002061036],"study_design_scores_gemma":[0.000005389493,0.0001042569,0.0006261466,0.000001884782,0.000004806744,0.00006765024,0.00000468707,0.000473984,0.9979693,0.00001538066,0.0007210265,0.00000560979],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9886601,0.001626827,0.006142096,0.0000744007,0.00002351312,0.00004859071,0.0005911415,0.0001652636,0.002668049],"genre_scores_gemma":[0.993409,0.0005094075,0.002969586,0.00004624228,0.000009163549,0.00003120467,0.0004909886,0.00002731814,0.002507191],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001708772,"threshold_uncertainty_score":0.005716443,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01189096196761662,"score_gpt":0.1795393155203261,"score_spread":0.1676483535527095,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}