{"id":"W2324614434","doi":"10.1021/ja210763n","title":"Tellurophenes with Delocalized π-Systems and Their Extended Valence Adducts","year":2012,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Organoselenium and organotellurium chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":89,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Delocalized electron; Valence (chemistry); Adduct; Chemical physics; Computational chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007166619,0.0001846239,0.0001135672,0.000127216,0.0001342015,0.000173926,0.0001899386,0.0002135906,0.001847924],"category_scores_gemma":[0.0001069202,0.0001245393,0.00007673069,0.0001379289,0.0001677535,0.0002437438,0.0002369886,0.0002235481,0.0002072619],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001229183,"about_ca_system_score_gemma":0.00008882069,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002185861,"about_ca_topic_score_gemma":0.0004876512,"domain_scores_codex":[0.9999646,0.000008743294,0.000001903963,0.000006008025,0.000008523382,0.00001010834],"domain_scores_gemma":[0.9999485,0.00001117123,0.00001658901,0.000008095554,0.000007299445,0.000008406396],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002783512,0.00003514861,0.0004243839,0.0001557879,0.00002260103,0.0002547383,0.0001124008,0.001367258,0.9865986,0.004664843,0.0001018765,0.005983965],"study_design_scores_gemma":[0.00003747416,0.0006924903,0.002259314,0.00001575363,0.00002711867,0.0003247248,0.00007227233,0.002455519,0.9873448,0.0009060967,0.005849285,0.00001518031],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9968647,0.0006108371,0.001236378,0.00003422998,0.000005301611,0.000003908066,0.00004721135,0.00001476265,0.00118265],"genre_scores_gemma":[0.9969447,0.0005975555,0.001047452,0.00002501002,0.000002643481,0.000006387857,0.00008103703,0.000004479843,0.001290769],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001847924,"threshold_uncertainty_score":0.006181896,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03660559792179015,"score_gpt":0.3358199689226395,"score_spread":0.2992143710008494,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}