{"id":"W2325182916","doi":"10.1021/om400166t","title":"Three-Coordinate, Cyclic Bent Allene Iron Complexes","year":2013,"lang":"en","type":"article","venue":"Organometallics","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":37,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Allene; Bent molecular geometry; Alkylation; Yield (engineering); Medicinal chemistry; Halide; Monomer; Trigonal bipyramidal molecular geometry; Stereochemistry; Crystallography; Crystal structure; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006952668,0.0002598679,0.0001482951,0.0001157484,0.0001588927,0.0002893804,0.0003707261,0.0002462631,0.001080336],"category_scores_gemma":[0.0001264934,0.000131585,0.00009196048,0.00007805638,0.0002311211,0.0001598426,0.0002583493,0.0004043639,0.0002859723],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003375888,"about_ca_system_score_gemma":0.0001284316,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007908778,"about_ca_topic_score_gemma":0.002546254,"domain_scores_codex":[0.9999344,0.000006704728,0.000003374492,0.00001312871,0.00002065369,0.00002174956],"domain_scores_gemma":[0.9999344,0.000007649055,0.00001287538,0.00000866673,0.00001247201,0.00002386106],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008978524,0.00003649655,0.0001645618,0.00008551743,0.00001185171,0.0001336647,0.000055346,0.0005158915,0.9937658,0.001693266,0.0002267948,0.003220923],"study_design_scores_gemma":[0.00004734504,0.0002826582,0.0007972373,0.000009395202,0.00001679969,0.0002616793,0.00002355161,0.001580761,0.9876,0.0002551272,0.009107168,0.00001835039],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.986205,0.0009055316,0.005385025,0.0001653328,0.00004982781,0.00003935675,0.0001796532,0.0001761783,0.006894002],"genre_scores_gemma":[0.9929658,0.0002952843,0.003744323,0.00004688899,0.000004828229,0.00001547645,0.000134348,0.00001235847,0.002780698],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001080336,"threshold_uncertainty_score":0.003614068,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01029536556300835,"score_gpt":0.2111092978259669,"score_spread":0.2008139322629585,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}