{"id":"W2325326107","doi":"10.1021/ja1075663","title":"Bodipy Dyes with Tunable Redox Potentials and Functional Groups for Further Tethering: Preparation, Electrochemical, and Spectroscopic Characterization","year":2010,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Luminescence and Fluorescent Materials","field":"Materials Science","cited_by":174,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"Canadian Institutes of Health Research","keywords":"Chemistry; BODIPY; Photochemistry; Moiety; Fluorescence; Redox; Nucleophile; Electrophile; HOMO/LUMO; Hydroxymethyl; Anthraquinone; Electrochemistry; Aryl; Photoinduced electron transfer; Biomolecule; Combinatorial chemistry; Molecule; Electron transfer; Organic chemistry; Electrode","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002916079,0.0001229161,0.0002602254,0.00001049733,0.0001182637,0.0001179457,0.00013808,0.00004971892,0.00005341111],"category_scores_gemma":[0.00007396276,0.00007324868,0.00008190024,0.00007385905,0.0003586403,0.0002142768,0.00004989817,0.0001403044,9.293508e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002665594,"about_ca_system_score_gemma":0.00005673384,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000004646349,"about_ca_topic_score_gemma":7.965816e-7,"domain_scores_codex":[0.9991211,0.00002307457,0.000273548,0.0001737224,0.0002099465,0.000198624],"domain_scores_gemma":[0.9991014,0.00005347794,0.0005069721,0.0001258442,0.0001391535,0.00007317619],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002471955,0.00004082401,0.00184471,0.00002259081,0.0000222386,1.529796e-7,0.0002384951,3.118423e-7,0.9971569,0.00002619001,0.0003428425,0.0000575295],"study_design_scores_gemma":[0.0004031571,0.0001446752,0.005565368,0.00002273555,0.00005012996,0.00006293031,0.0000818191,0.00004493088,0.9927554,0.0002919686,0.0004764307,0.0001004127],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9964356,0.0000202098,0.001922135,0.001269872,0.0001701378,0.0001579288,0.000006158758,0.00001254093,0.000005349752],"genre_scores_gemma":[0.9930595,0.00004772219,0.005976278,0.0003093045,0.0005306157,0.000009364407,0.000004394138,0.00001443401,0.0000484331],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004401478,"threshold_uncertainty_score":0.2986995,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005431506049607091,"score_gpt":0.2268199630537814,"score_spread":0.2213884570041743,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}