{"id":"W2325397456","doi":"10.1021/om2005172","title":"Stereoelectronic Factors in Iron Catalysis: Synthesis and Characterization of Aryl-Substituted Iron(II) Carbonyl P–N–N–P Complexes and Their Use in the Asymmetric Transfer Hydrogenation of Ketones","year":2011,"lang":"en","type":"article","venue":"Organometallics","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":121,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Tetrafluoroborate; Aryl; Acetophenone; Catalysis; Phosphonium; Trifluoromethyl; Medicinal chemistry; Transfer hydrogenation; Stereochemistry; Organic chemistry; Ionic liquid; Alkyl","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002054975,0.0002417499,0.0001637358,0.00009894485,0.0001374661,0.000280512,0.0002956731,0.0003048617,0.0006244075],"category_scores_gemma":[0.0003089186,0.0001714317,0.00009628036,0.0001102331,0.0002134219,0.0001659733,0.0001450318,0.0003002603,0.0001844717],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002545359,"about_ca_system_score_gemma":0.0001252567,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007216907,"about_ca_topic_score_gemma":0.00113715,"domain_scores_codex":[0.9998183,0.00004780783,0.00001435304,0.0000332412,0.00005393408,0.0000323688],"domain_scores_gemma":[0.9998673,0.00002232625,0.00003117864,0.00001538701,0.00002768382,0.00003604815],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002003717,0.00003282491,0.0001863862,0.00003154682,0.00000429366,0.00006350592,0.00002850096,0.000183043,0.9979743,0.00006130506,0.00003504435,0.001198883],"study_design_scores_gemma":[0.00002511631,0.0003803821,0.00108918,0.000002844565,0.000009875192,0.0001127244,0.00001495474,0.0005845768,0.9970444,0.00001160711,0.0007197281,0.000004727809],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9959369,0.0004519035,0.001396651,0.00004140456,0.000009397313,0.00004030377,0.00007942427,0.00003445754,0.002009592],"genre_scores_gemma":[0.998015,0.0001584554,0.0009430757,0.00001297135,0.000003662069,0.00001333783,0.00006520805,0.000007104551,0.0007810566],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007216907,"threshold_uncertainty_score":0.002088904,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02234065351568443,"score_gpt":0.198378753329314,"score_spread":0.1760380998136296,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}