{"id":"W2325405021","doi":"10.1021/ja409657y","title":"Surface-Induced Alkene Oligomerization: Does Thermal Hydrosilylation Really Lead to Monolayer Protected Silicon Nanocrystals?","year":2013,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Silicon Nanostructures and Photoluminescence","field":"Materials Science","cited_by":102,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Hydrosilylation; Chemistry; Alkene; Ligand (biochemistry); Monolayer; Photochemistry; Hydride; Silylation; Silicon; Inert gas; Polymer chemistry; Hydrogen; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001413584,0.0001762599,0.0001396662,0.00005577626,0.00007776766,0.000171441,0.0001411901,0.0002243011,0.0008922151],"category_scores_gemma":[0.0001986943,0.000113046,0.000213023,0.00004711565,0.0002120297,0.0002398894,0.000120208,0.0002170108,0.0001741241],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001676903,"about_ca_system_score_gemma":0.0001163992,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003719513,"about_ca_topic_score_gemma":0.0006841378,"domain_scores_codex":[0.9999369,0.000008237434,0.000003762,0.00001586663,0.00001650202,0.00001864286],"domain_scores_gemma":[0.9999062,0.00003530425,0.00002225626,0.00001300846,0.00001308721,0.00001006876],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002079899,0.00000523008,0.0001082342,0.00001793965,0.000002582345,0.00001924416,0.00001338011,0.00004113141,0.9992367,0.00004295393,0.000006180156,0.0004855595],"study_design_scores_gemma":[0.000001529413,0.00003936749,0.0004823254,0.000001027186,0.000002503697,0.00002141543,0.000009225186,0.0002208701,0.9990844,0.000009558065,0.0001269851,8.462322e-7],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9971649,0.00033137,0.001565481,0.00003678141,0.000005318188,0.00001094737,0.00004361307,0.00001997243,0.000821617],"genre_scores_gemma":[0.9984496,0.0002161879,0.0007394962,0.00001842822,0.000002015014,0.000006551498,0.00005927645,0.000008693491,0.0004998063],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008922151,"threshold_uncertainty_score":0.002984762,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009412696250231271,"score_gpt":0.2376215996330789,"score_spread":0.2282089033828476,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}