{"id":"W2325483543","doi":"10.1021/ie400888p","title":"Synthesis and Thermal Decomposition Behavior of Zircoaluminate Coupling Agents","year":2013,"lang":"en","type":"article","venue":"Industrial & Engineering Chemistry Research","topic":"Silicone and Siloxane Chemistry","field":"Materials Science","cited_by":26,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of New Brunswick","funders":"Ministry of Education of the People's Republic of China","keywords":"Thermal decomposition; Chemistry; Mass spectrometry; Decomposition; Matrix-assisted laser desorption/ionization; Fourier transform infrared spectroscopy; Desorption; Chemical process of decomposition; Nuclear chemistry; Analytical Chemistry (journal); Chemical engineering; Chromatography; Organic chemistry; Adsorption","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00065617,0.0001483838,0.0002235084,0.0000491902,0.00008921104,0.0001009565,0.0002843588,0.0002526387,0.001351097],"category_scores_gemma":[0.0004435128,0.0001508577,0.00004318817,0.0001730181,0.0001442576,0.0001445167,0.0001534436,0.0004137651,0.00003571741],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007049469,"about_ca_system_score_gemma":0.00006498907,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001488548,"about_ca_topic_score_gemma":8.190583e-8,"domain_scores_codex":[0.9985058,0.00001972277,0.0002942932,0.0002998251,0.0004455953,0.0004347113],"domain_scores_gemma":[0.9989861,0.0003330864,0.00005606121,0.0002836391,0.0001687396,0.0001723629],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001284593,0.00004743981,0.0009937582,0.00009301295,0.000008089266,0.000009293529,0.0000345931,0.0003521292,0.9978399,0.000001656349,0.0001376861,0.0004696122],"study_design_scores_gemma":[0.0002805267,0.00001461352,0.001040793,0.0001154442,0.00001389873,0.00001296189,0.00008968901,0.001364002,0.9968908,0.000002401558,0.0000356875,0.0001391651],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9992682,0.0000694364,0.000001484083,0.00004740969,0.00007573811,0.000204058,0.000015536,0.00005195787,0.0002662341],"genre_scores_gemma":[0.9993443,0.000008651624,0.00003625843,0.000001398658,0.0002647113,0.0001696668,0.000006892752,0.00002350151,0.0001445483],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001315379,"threshold_uncertainty_score":0.9995618,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0765563658127337,"score_gpt":0.3338578578476239,"score_spread":0.2573014920348902,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}