{"id":"W2325712912","doi":"10.1021/om401000s","title":"Reactions of CO<sub>2</sub> with Heteroleptic Zinc and Zinc–NHC Complexes","year":2013,"lang":"en","type":"article","venue":"Organometallics","topic":"Carbon dioxide utilization in catalysis","field":"Chemical Engineering","cited_by":29,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Zinc; Carbene; IMes; Monomer; Ligand (biochemistry); Medicinal chemistry; Stereochemistry; Organic chemistry; Receptor; Polymer; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006381635,0.0001825153,0.0003105069,0.0001524121,0.00004354098,0.00004072177,0.0001339654,0.00008275364,0.0004365281],"category_scores_gemma":[0.00008380318,0.0001691641,0.00006395941,0.0004650957,0.0001526367,0.0001995045,0.0000634501,0.0001345212,0.0001040065],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004973949,"about_ca_system_score_gemma":0.00001744445,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004824643,"about_ca_topic_score_gemma":0.00002099747,"domain_scores_codex":[0.9989555,0.0000150726,0.0003376834,0.0002505167,0.0002322373,0.0002090024],"domain_scores_gemma":[0.9991308,0.0001205818,0.0001284489,0.000358937,0.0001304565,0.0001307804],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000004657147,0.00004643801,0.001425817,0.00008743415,0.0001174574,9.586877e-7,0.00009153416,0.0004768838,0.9963424,0.0009212897,0.00008306767,0.0004021293],"study_design_scores_gemma":[0.0004658444,0.0000446394,0.005378807,0.00003944135,0.000124994,0.00002905427,0.0001143292,0.006281826,0.9858088,0.000149895,0.001271251,0.0002911171],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9938189,0.00007830968,0.004158463,0.0001039421,0.00003023974,0.00016512,0.00002080782,0.0001192628,0.001504924],"genre_scores_gemma":[0.9985701,0.00005784889,0.0009207651,0.00004164686,0.00003407715,0.00002948574,0.0000610352,0.00005146867,0.0002335211],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01053353,"threshold_uncertainty_score":0.6898313,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01063206018998446,"score_gpt":0.2128114610442865,"score_spread":0.202179400854302,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}