{"id":"W2325797793","doi":"10.1021/om1009044","title":"Deprotonation and Addition Reactions of Frustrated Lewis Pairs with Alkynes","year":2010,"lang":"en","type":"article","venue":"Organometallics","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":211,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Deprotonation; Lewis acids and bases; Borane; Frustrated Lewis pair; Phosphine; Medicinal chemistry; Salt (chemistry); Stereochemistry; Catalysis; Organic chemistry; Ion","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00006930735,0.0001698039,0.0001795658,0.00005400298,0.00008495485,0.00003456672,0.0001145319,0.0002049312,0.007553962],"category_scores_gemma":[0.00009436365,0.0001539989,0.00003369315,0.0002456951,0.0001783803,0.0001717191,0.00002980324,0.0003012568,0.00001409522],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001922741,"about_ca_system_score_gemma":0.00007472093,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004313072,"about_ca_topic_score_gemma":0.0001137538,"domain_scores_codex":[0.9991269,0.000005979809,0.000244668,0.0002730275,0.000187203,0.0001622073],"domain_scores_gemma":[0.999221,0.00005361744,0.000167626,0.000315444,0.0001310611,0.0001112946],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001501604,0.0001204826,0.009197822,0.0001716179,0.00004110618,0.000002512397,0.00006949427,5.473123e-7,0.9878591,0.0004411851,0.00005731319,0.002023816],"study_design_scores_gemma":[0.0004390976,0.00002203431,0.005822313,0.00002276991,0.00004862513,0.00005433523,0.0002023239,0.0000304117,0.9859496,0.0001120622,0.007110311,0.0001860766],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9923292,0.00002808871,0.00002690249,0.0001780723,0.00003978099,0.00008331174,0.00007085153,0.0001139236,0.00712986],"genre_scores_gemma":[0.9979917,0.00004900467,0.0007690546,0.00002059476,0.00009292322,0.00002292021,0.0001567346,0.00003774901,0.000859287],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007539867,"threshold_uncertainty_score":0.9933532,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007250628028623209,"score_gpt":0.2066130858769874,"score_spread":0.1993624578483642,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}