{"id":"W2325797793","doi":"10.1021/om1009044","title":"Deprotonation and Addition Reactions of Frustrated Lewis Pairs with Alkynes","year":2010,"lang":"en","type":"article","venue":"Organometallics","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":211,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Deprotonation; Lewis acids and bases; Borane; Frustrated Lewis pair; Phosphine; Medicinal chemistry; Salt (chemistry); Stereochemistry; Catalysis; Organic chemistry; Ion","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001725426,0.0004046058,0.0003250851,0.0001791764,0.0002786692,0.0003537393,0.0004722312,0.0003748008,0.002359389],"category_scores_gemma":[0.0001922145,0.0002183768,0.00026127,0.0001766467,0.0002593624,0.0003516747,0.0006764579,0.0005696697,0.0005636678],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003272983,"about_ca_system_score_gemma":0.0001568451,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004652829,"about_ca_topic_score_gemma":0.0009695034,"domain_scores_codex":[0.999814,0.00002111685,0.00001081367,0.00002757741,0.00004197802,0.00008460011],"domain_scores_gemma":[0.999923,0.00001417213,0.00001477837,0.0000170997,0.000008731139,0.000022263],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000326302,0.00005926831,0.0001473807,0.0001732838,0.00002914932,0.0003472225,0.0002332173,0.001020543,0.9897475,0.004236802,0.0002901368,0.003389156],"study_design_scores_gemma":[0.00008311774,0.0004126951,0.0004259138,0.000007727785,0.00001037039,0.0002160213,0.00003998296,0.002029129,0.992942,0.0004191881,0.003386745,0.0000271905],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9923046,0.0003063636,0.002330895,0.00005839167,0.00002891094,0.00004449089,0.00009852191,0.0000707436,0.004757117],"genre_scores_gemma":[0.994848,0.0003879285,0.001677548,0.00003786994,0.000007881576,0.00003446256,0.00009946741,0.00002081182,0.002886138],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002359389,"threshold_uncertainty_score":0.007892966,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007250628028623209,"score_gpt":0.2066130858769874,"score_spread":0.1993624578483642,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}