{"id":"W2325843513","doi":"10.1021/ja306047u","title":"Interrogating Near-Infrared Electrogenerated Chemiluminescence of Au<sub>25</sub>(SC<sub>2</sub>H<sub>4</sub>Ph)<sub>18</sub><sup>+</sup> Clusters","year":2012,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Nanocluster Synthesis and Applications","field":"Materials Science","cited_by":146,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Chemistry; Excited state; Spectroscopy; Photoluminescence; HOMO/LUMO; Chemiluminescence; Near-infrared spectroscopy; Ground state; Photochemistry; Luminescence; Analytical Chemistry (journal); Molecule; Atomic physics; Optoelectronics; Physical chemistry; Optics; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.001797897,0.0008508788,0.00154279,0.00009629975,0.0006262569,0.0002390416,0.002030783,0.0003550611,0.00003033456],"category_scores_gemma":[0.000690731,0.0006812185,0.001578014,0.001655212,0.001750995,0.0007250087,0.0008218471,0.001227991,0.00006290433],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001041899,"about_ca_system_score_gemma":0.0006584245,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003893875,"about_ca_topic_score_gemma":0.000006872612,"domain_scores_codex":[0.9935139,0.0003911488,0.002132106,0.0008111835,0.00143813,0.001713493],"domain_scores_gemma":[0.9933214,0.0006458907,0.003427675,0.001137442,0.0006872216,0.0007804381],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001530069,0.000453968,0.0009465776,0.00009225679,0.0002206028,0.000002810196,0.002315579,0.0001599347,0.9800774,0.00000825441,0.009573053,0.005996601],"study_design_scores_gemma":[0.0008874326,0.0001458365,0.0004465981,0.0003348981,0.0003223742,0.0001911659,0.00165852,0.002308609,0.9926696,0.00007086638,0.0002359795,0.0007281267],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9962456,0.0003136943,0.001022859,0.001277554,0.0003704066,0.0005183247,0.00007246198,0.0001076017,0.00007153796],"genre_scores_gemma":[0.9942136,0.0003185818,0.002502419,0.001503671,0.001220047,0.00007629005,0.00001698315,0.0001421449,0.000006194135],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01259224,"threshold_uncertainty_score":0.9995639,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01237105551506165,"score_gpt":0.2393118678802054,"score_spread":0.2269408123651437,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}