{"id":"W2325894832","doi":"10.1021/la301975u","title":"Photoinduced Carbene Generation from Diazirine Modified Task Specific Phosphonium Salts To Prepare Robust Hydrophobic Coatings","year":2012,"lang":"en","type":"article","venue":"Langmuir","topic":"Surface Modification and Superhydrophobicity","field":"Materials Science","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Diazirine; Chemistry; Carbene; Covalent bond; Phosphonium; Superhydrophobic coating; Contact angle; Coating; Aryl; Polymer chemistry; Chemical engineering; Photochemistry; Organic chemistry; Catalysis; Alkyl","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.0003673353,0.0002869102,0.0003373185,0.0000747087,0.00026213,0.0001367689,0.000338545,0.0001433795,0.001435991],"category_scores_gemma":[0.00004148825,0.000267587,0.0000809635,0.0002942833,0.00005979909,0.000315917,0.0001222001,0.000118671,0.001580706],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001736584,"about_ca_system_score_gemma":0.00003457619,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001592611,"about_ca_topic_score_gemma":0.0001483181,"domain_scores_codex":[0.997842,0.0001367541,0.0004152612,0.0005843437,0.0004322828,0.0005893827],"domain_scores_gemma":[0.9987701,0.00004626488,0.0001233147,0.000644107,0.00009977512,0.0003164423],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004941988,0.0001160853,0.0006521342,0.000005180067,0.000005100287,0.000002657427,0.002644629,0.00128288,0.9851349,0.0001865315,0.009819441,0.0001010327],"study_design_scores_gemma":[0.0005141234,0.00003390244,0.01120267,0.00001131571,0.00001532939,0.000003535023,0.0001692372,0.002347926,0.9700756,0.0000183024,0.01521388,0.0003941923],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9939727,0.0003522859,0.001511949,0.0003680246,0.001364557,0.0005745715,0.0001873291,0.0002719725,0.00139667],"genre_scores_gemma":[0.9940816,0.00001539166,0.003332609,0.0005974708,0.0007992251,0.000127186,0.0002806063,0.00005059969,0.0007153134],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01505931,"threshold_uncertainty_score":0.9999776,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05263829724345254,"score_gpt":0.2508191783277781,"score_spread":0.1981808810843255,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}