{"id":"W2325992237","doi":"10.1021/ja412650s","title":"Reversible Interconversion Between a Monomeric Iridium Hydroxo and a Dinuclear Iridium μ-Oxo Complex","year":2014,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":57,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"","keywords":"Chemistry; Iridium; Ligand (biochemistry); Monomer; Proton NMR; Photochemistry; Infrared spectroscopy; HOMO/LUMO; Crystallography; Molecule; Stereochemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001729681,0.0002284592,0.0002020364,0.00008805478,0.0001017491,0.0003202711,0.0006019421,0.0001965884,0.001542851],"category_scores_gemma":[0.0002677239,0.000174888,0.0000927164,0.0001063696,0.0001736966,0.0002237703,0.0003337404,0.0004295777,0.0003523143],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003139282,"about_ca_system_score_gemma":0.0001024466,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003552433,"about_ca_topic_score_gemma":0.0005100112,"domain_scores_codex":[0.9998404,0.00002288365,0.000008275431,0.00005004302,0.00003394179,0.00004444352],"domain_scores_gemma":[0.9999375,0.00001034839,0.00001748304,0.000008174963,0.000007892782,0.00001856374],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002162076,0.0000210095,0.0001311337,0.00009796108,0.00001181903,0.00006963779,0.00008219443,0.0001407745,0.9945168,0.0004474783,0.0002493628,0.004015479],"study_design_scores_gemma":[0.00004195122,0.000266531,0.0007488296,0.000007573148,0.00001064191,0.0001405531,0.00003484844,0.0005786021,0.9947557,0.00005608798,0.003350772,0.000007838892],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9914334,0.0005547894,0.003002854,0.00006186552,0.00002720652,0.00002325346,0.00009322637,0.0001329601,0.004670568],"genre_scores_gemma":[0.9962931,0.0001597102,0.001422317,0.00003888642,0.000007125404,0.00001353373,0.0001237752,0.00002324283,0.001918254],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001542851,"threshold_uncertainty_score":0.005161285,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01380640000552913,"score_gpt":0.2225158717629368,"score_spread":0.2087094717574077,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}