{"id":"W2326070855","doi":"10.1021/ja002417a","title":"Electrochemically Induced C−Br and C−I Bond Activation by the Pd<sub>3</sub>(dppm)<sub>3</sub>CO<sup>2+</sup> Cluster, and Characterization of the Reactive Pd<sub>3</sub>(dppm)<sub>3</sub>CO<sup>+</sup> Intermediate:  The First Confidently Identified Paramagnetic Pd Cluster","year":2001,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Nanocluster Synthesis and Applications","field":"Materials Science","cited_by":27,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"","keywords":"Chemistry; Cluster (spacecraft); Palladium; Characterization (materials science); Crystallography; Catalysis; Nanotechnology; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.001991463,0.001026853,0.001407634,0.0001301574,0.001182917,0.000709228,0.00228227,0.0005208622,0.00001483697],"category_scores_gemma":[0.0006899037,0.0006315678,0.0009516148,0.001346234,0.002502425,0.0009458655,0.0008864444,0.001898274,0.00002656249],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006010019,"about_ca_system_score_gemma":0.000334303,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006260788,"about_ca_topic_score_gemma":0.00001879539,"domain_scores_codex":[0.9929287,0.0007760172,0.002150618,0.001158814,0.001744817,0.00124104],"domain_scores_gemma":[0.9919834,0.001665485,0.003771186,0.001460572,0.0006817585,0.000437663],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005906829,0.0003798591,0.0006266622,0.00008061594,0.000263679,0.000001692371,0.003223371,0.00003991814,0.9803388,0.00001567051,0.01000743,0.004431589],"study_design_scores_gemma":[0.001719423,0.000226928,0.00696442,0.0003313226,0.0004822275,0.0002755907,0.001942923,0.002018944,0.9841888,0.0003332396,0.0008036223,0.0007125858],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9867637,0.0001540183,0.0006880463,0.01030923,0.0002339569,0.001577895,0.0001417559,0.00007194866,0.00005946813],"genre_scores_gemma":[0.9929235,0.001467274,0.00007800371,0.004380242,0.0007270246,0.0002026469,0.00005380863,0.0001465054,0.00002099722],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009203809,"threshold_uncertainty_score":0.9996136,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007623754059026151,"score_gpt":0.2255818542752832,"score_spread":0.2179581002162571,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}