{"id":"W2326088418","doi":"10.1021/om4005516","title":"Univalent Gallium Salts of Weakly Coordinating Anions: Effective Initiators/Catalysts for the Synthesis of Highly Reactive Polyisobutylene","year":2013,"lang":"en","type":"article","venue":"Organometallics","topic":"Carbon dioxide utilization in catalysis","field":"Chemical Engineering","cited_by":86,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Deutsche Forschungsgemeinschaft","keywords":"Chemistry; Gallium; Polymerization; Isobutylene; Reactivity (psychology); Polymer chemistry; Toluene; Catalysis; Solvent; Ligand (biochemistry); Cationic polymerization; Solution polymerization; Organic chemistry; Polymer; Copolymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002525676,0.0006717034,0.0003100714,0.0002699186,0.0001170473,0.0004361306,0.0004465449,0.0004190756,0.0009787248],"category_scores_gemma":[0.0002473625,0.000355563,0.0002414323,0.0002281014,0.0002093994,0.0003791783,0.0005513103,0.0007594693,0.0007253803],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001920341,"about_ca_system_score_gemma":0.0001753731,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002401132,"about_ca_topic_score_gemma":0.0005277558,"domain_scores_codex":[0.9997876,0.00003374497,0.00002314721,0.0000478654,0.00006657467,0.00004100315],"domain_scores_gemma":[0.9998914,0.00001596389,0.00003672036,0.00001328902,0.00001630137,0.00002631393],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002819343,0.000008740968,0.0000295448,0.00005681955,0.000003663335,0.00001962098,0.00001364661,0.00006250998,0.9984724,0.00009637396,0.00001681304,0.001191586],"study_design_scores_gemma":[0.000009327538,0.00004864448,0.0001173284,0.000004261349,0.000008393875,0.00003667192,0.000004618086,0.0002820111,0.9982088,0.00001998173,0.001255452,0.000004622113],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9730525,0.004438794,0.01881667,0.0001110062,0.00006953401,0.00008376923,0.0002065578,0.0002966005,0.002924546],"genre_scores_gemma":[0.9766759,0.002435248,0.01669026,0.00004607646,0.00002608156,0.0000633735,0.0001937181,0.0001366373,0.003732715],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009787248,"threshold_uncertainty_score":0.003274202,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009214725877397075,"score_gpt":0.2284570389112922,"score_spread":0.2192423130338951,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}