{"id":"W2326777612","doi":"10.1021/ic501831j","title":"Xenon(IV)–Carbon Bond of [C<sub>6</sub>F<sub>5</sub>XeF<sub>2</sub>]<sup>+</sup>; Structural Characterization and Bonding of [C<sub>6</sub>F<sub>5</sub>XeF<sub>2</sub>][BF<sub>4</sub>], [C<sub>6</sub>F<sub>5</sub>XeF<sub>2</sub>][BF<sub>4</sub>]·2HF, and [C<sub>6</sub>F<sub>5</sub>XeF<sub>2</sub>][BF<sub>4</sub>]·<i>n</i>NCCH<sub>3</sub>(<i>n</i>= 1, 2); and the Fluorinating Properties of [C<sub>6</sub>F<sub>5</sub>XeF<sub>2</sub>][BF<sub>4</sub>]","year":2014,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"Deutsche Forschungsgemeinschaft; Natural Sciences and Engineering Research Council of Canada; Verband der Chemischen Industrie","keywords":"Chemistry; Nuclear magnetic resonance spectroscopy; Crystallography; Raman spectroscopy; NMR spectra database; Fluorine-19 NMR; Triple bond; Molecule; Solvent; Stereochemistry; Spectral line; Double bond; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006926429,0.0002255731,0.00009355952,0.0001366278,0.0003594238,0.0001311997,0.0003401512,0.0003756543,0.005784707],"category_scores_gemma":[0.0001830193,0.00008338512,0.00007707448,0.0001827334,0.0002422941,0.0002353906,0.0002294564,0.0002867928,0.0003182801],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002257601,"about_ca_system_score_gemma":0.0001964067,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002458975,"about_ca_topic_score_gemma":0.00366375,"domain_scores_codex":[0.9999214,0.00000547101,0.000002660246,0.00001649182,0.00003254722,0.00002145133],"domain_scores_gemma":[0.9999475,0.000006347029,0.00001286912,0.000009052869,0.00001332159,0.00001086699],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004469008,0.00002415633,0.001355289,0.0003184422,0.00002297599,0.0002871787,0.0002300927,0.0006671917,0.9817504,0.003513711,0.001511432,0.009872117],"study_design_scores_gemma":[0.00001659949,0.0002386335,0.009487476,0.00002716713,0.00001340172,0.0004396558,0.0002516546,0.001364203,0.972388,0.0006057727,0.01514338,0.00002396664],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9875827,0.0008022977,0.002049671,0.0001138339,0.00003814309,0.00001565346,0.0004366371,0.00004115628,0.008919862],"genre_scores_gemma":[0.9943975,0.0002464654,0.000980355,0.00003550525,0.000005934072,0.000009550827,0.0006431137,0.00001821102,0.00366346],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005784707,"threshold_uncertainty_score":0.01935184,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01718210224634812,"score_gpt":0.255077087823957,"score_spread":0.2378949855776089,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}