{"id":"W2327175958","doi":"10.1021/ol200051m","title":"Topochemical Polymerization of a Diarylbutadiyne Derivative in the Gel and Solid States","year":2011,"lang":"en","type":"article","venue":"Organic Letters","topic":"Polydiacetylene-based materials and applications","field":"Chemistry","cited_by":62,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"","keywords":"Thermochromism; Chemistry; Polymerization; Derivative (finance); Scanning electron microscope; Polymer chemistry; Chemical engineering; Organic chemistry; Polymer; Materials science","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001326853,0.0003007786,0.0001618634,0.0001573464,0.000125984,0.0001883047,0.0001605899,0.0002147835,0.00136756],"category_scores_gemma":[0.0001496873,0.0001693248,0.0001778182,0.0001174638,0.0002044248,0.0002177559,0.0001709771,0.0005308705,0.0003776932],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002754816,"about_ca_system_score_gemma":0.000244843,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005716861,"about_ca_topic_score_gemma":0.00118639,"domain_scores_codex":[0.9999161,0.000007827661,0.000005150747,0.00002502234,0.00002281396,0.00002321009],"domain_scores_gemma":[0.9999031,0.0000243032,0.00002095313,0.00001629244,0.00001251477,0.00002277768],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001264773,0.000007001441,0.00001541492,0.00002389796,0.000001626407,0.00001978086,0.000008814379,0.00002455002,0.9990256,0.0001405809,0.00002228442,0.0006977961],"study_design_scores_gemma":[0.000004441335,0.00005178554,0.0001830858,0.000001763004,0.000002556167,0.00003316519,0.000002441676,0.0001936591,0.9985448,0.00001826591,0.0009622537,0.000001919213],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9592218,0.003003347,0.02678292,0.0002257743,0.0001170145,0.00007600496,0.0003219357,0.0002982806,0.009952814],"genre_scores_gemma":[0.9847109,0.0009113624,0.009508498,0.00006596003,0.00001338556,0.00003337773,0.0001336048,0.00005363627,0.004569261],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00136756,"threshold_uncertainty_score":0.004574955,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009805363027149948,"score_gpt":0.2082470738418858,"score_spread":0.1984417108147358,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}