{"id":"W2327303995","doi":"10.1021/om400645s","title":"A Tris(triphenylphosphine)aluminum Ambiphilic Precatalyst for the Reduction of Carbon Dioxide with Catecholborane","year":2013,"lang":"en","type":"article","venue":"Organometallics","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":127,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"","keywords":"Chemistry; Borane; Triphenylphosphine; Adduct; Medicinal chemistry; Synthon; Selective reduction; Methanol; Catalysis; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008832364,0.0002699322,0.0001803567,0.0002172107,0.0001518204,0.0002297283,0.0003319343,0.000256903,0.0008443921],"category_scores_gemma":[0.00009434217,0.0002107988,0.0001195904,0.0001195072,0.0002039741,0.0001767141,0.0003070248,0.0003540129,0.0003876688],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000355793,"about_ca_system_score_gemma":0.0002772252,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005471439,"about_ca_topic_score_gemma":0.001795516,"domain_scores_codex":[0.9999135,0.000006761594,0.000006430716,0.00001695784,0.00003656242,0.00001980993],"domain_scores_gemma":[0.9999487,0.000004140179,0.0000137544,0.000007834248,0.00001017941,0.0000153981],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002337489,0.00001109699,0.0000443052,0.00006844106,0.000003937155,0.00006288901,0.00001856694,0.00006371345,0.9977737,0.0002041955,0.00005940129,0.00166631],"study_design_scores_gemma":[0.000006632027,0.00009274845,0.0003047111,0.000002864836,0.000006396054,0.00009233593,0.00000729676,0.0002320892,0.996437,0.00002220905,0.00279184,0.00000388942],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9747771,0.00223291,0.0127639,0.0001556035,0.00008044353,0.0001087294,0.0003365748,0.000559545,0.008985266],"genre_scores_gemma":[0.9844459,0.001106188,0.009838202,0.00005524547,0.0000126139,0.00005166897,0.0003059034,0.00007239959,0.004112058],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008443921,"threshold_uncertainty_score":0.002824783,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009576169995094957,"score_gpt":0.2084982439733526,"score_spread":0.1989220739782577,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}