{"id":"W2327391571","doi":"10.1021/ma301667c","title":"Self-Immolative Polymers Containing Rapidly Cyclizing Spacers: Toward Rapid Depolymerization Rates","year":2012,"lang":"en","type":"article","venue":"Macromolecules","topic":"Dendrimers and Hyperbranched Polymers","field":"Materials Science","cited_by":80,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Depolymerization; Polymer; Nucleophile; Chemistry; Cleavage (geology); Electrophile; Polymer chemistry; Limiting; Homogeneous; Organic chemistry; Materials science; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003614162,0.0004984164,0.0001785488,0.000249437,0.00009382048,0.0003141135,0.0002399963,0.0002673248,0.0008720683],"category_scores_gemma":[0.0004313082,0.0002335739,0.0001702795,0.0001494708,0.0002502104,0.0005627051,0.0002163311,0.0005963817,0.0003638791],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002768412,"about_ca_system_score_gemma":0.0002062134,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001423846,"about_ca_topic_score_gemma":0.0003068545,"domain_scores_codex":[0.9998443,0.00003213523,0.00001640628,0.0000366321,0.00004097549,0.00002943657],"domain_scores_gemma":[0.9995821,0.0001117289,0.00017546,0.00003271306,0.00004143746,0.00005654455],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001999522,0.00001396296,0.00004098753,0.00002342952,0.000001764608,0.00001338108,0.00001440034,0.0001322199,0.9980676,0.0002010648,0.00001105594,0.001460181],"study_design_scores_gemma":[0.000003323833,0.00005743745,0.0001064232,0.000001592337,0.000002575543,0.00002163174,0.000001686179,0.0004009022,0.9988558,0.00001524121,0.0005313705,0.000001933287],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9734924,0.001657921,0.02203676,0.0001082773,0.00002470107,0.00007740437,0.00007728303,0.0002618511,0.002263372],"genre_scores_gemma":[0.9755968,0.001258523,0.02094231,0.00004668414,0.00001640082,0.00005985696,0.00009639345,0.00006211817,0.001920764],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008720683,"threshold_uncertainty_score":0.002917409,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01804174983533815,"score_gpt":0.2610333173806926,"score_spread":0.2429915675453544,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}