{"id":"W2327394776","doi":"10.1021/la303659c","title":"Crankshafts: Using Simple, Flat<i>C</i><sub>2<i>h</i></sub>-Symmetric Molecules to Direct the Assembly of Chiral 2D Nanopatterns","year":2012,"lang":"en","type":"article","venue":"Langmuir","topic":"Surface Chemistry and Catalysis","field":"Engineering","cited_by":12,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Molecule; Intermolecular force; Enantiomer; Chirality (physics); Chemistry; Chemical physics; Hydrogen bond; Adsorption; Crankshaft; Affinities; Nanotechnology; Crystallography; Stereochemistry; Materials science; Physics; Thermodynamics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001895015,0.0002030744,0.0002550293,0.00008992208,0.00007232936,0.00002213685,0.0002401132,0.00008446586,0.00002208394],"category_scores_gemma":[0.0000494026,0.0001642959,0.0001314558,0.0007419115,0.00002422243,0.0001305487,0.0000715554,0.0001309115,0.00004993423],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004850492,"about_ca_system_score_gemma":0.000007160287,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001885911,"about_ca_topic_score_gemma":0.000005593585,"domain_scores_codex":[0.9989434,0.00002797765,0.0002298494,0.0001503775,0.0002229083,0.0004254224],"domain_scores_gemma":[0.9993724,0.00009571789,0.00004639292,0.0003455452,0.0000313111,0.0001086227],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000006060425,0.00002124887,0.003907564,0.00008987665,0.00009305154,0.000002774196,0.0004244172,0.003139753,0.9892694,0.00001365204,0.0006958021,0.002336432],"study_design_scores_gemma":[0.0001180712,0.000007268128,0.006980598,0.00002033016,0.00007749282,0.000008646796,0.0001189458,0.000841646,0.9902977,0.000007919215,0.001305721,0.0002156665],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9923594,0.001030077,0.0008926894,0.00002712702,0.0001855155,0.00009972228,0.00005462766,0.0001478593,0.005202964],"genre_scores_gemma":[0.9993561,0.00001989775,0.0001909668,0.0001136444,0.0002015497,0.00001507039,0.00002604786,0.00004672621,0.00003001847],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006996661,"threshold_uncertainty_score":0.6699791,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0125304647491082,"score_gpt":0.2237648553618433,"score_spread":0.2112343906127351,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}