{"id":"W2327753127","doi":"10.1021/ic101986a","title":"Changing the Role of 2,2′-Bipyridine from Secondary Ligand to Protagonist in [Ru(bpy)<sub>2</sub>(N−N)]<sup>2+</sup> Complexes: Low-Energy, Red Emission from a Ruthenium(II)-to-2,2′-Bipyridine <sup>3</sup>MLCT State","year":2010,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Ruthenium; Chemistry; Bipyridine; Denticity; Electrochemistry; Ligand (biochemistry); Crystallography; 2,2'-Bipyridine; Guanidine; Fluorescence; Stereochemistry; Photochemistry; Crystal structure; Catalysis; Physical chemistry; Electrode; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0007136324,0.0008553432,0.001431671,0.0002328402,0.0004398238,0.0001415566,0.001009586,0.0004074094,0.001889716],"category_scores_gemma":[0.0007540144,0.0006559161,0.0003284576,0.0009598143,0.0002582583,0.0001797725,0.0009825238,0.00128142,0.00007382133],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001830093,"about_ca_system_score_gemma":0.0004459487,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001066288,"about_ca_topic_score_gemma":0.0001175298,"domain_scores_codex":[0.9953735,0.0001250149,0.001389068,0.001250705,0.0008095619,0.001052138],"domain_scores_gemma":[0.9964187,0.0003781797,0.0003893249,0.001836417,0.0002835538,0.0006938471],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001198968,0.0003675319,0.0006755054,0.000218459,0.0002033825,0.00003097255,0.007340775,0.0001154615,0.9821171,0.000009661573,0.000820675,0.006901536],"study_design_scores_gemma":[0.001923282,0.0001897826,0.0004141538,0.0008732998,0.0001480687,0.00005007564,0.002394109,0.004606971,0.9757456,0.000861394,0.01208483,0.0007084135],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9937038,0.0007581096,0.00003622415,0.001845352,0.0001183687,0.001007494,0.0006507761,0.0001673263,0.001712581],"genre_scores_gemma":[0.9963864,0.00006223451,0.0003886622,0.000697902,0.0009959533,0.0001908025,0.000490196,0.0001909022,0.0005969425],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01126415,"threshold_uncertainty_score":0.9995892,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00928651809591921,"score_gpt":0.2104179428724624,"score_spread":0.2011314247765432,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}