{"id":"W2327753127","doi":"10.1021/ic101986a","title":"Changing the Role of 2,2′-Bipyridine from Secondary Ligand to Protagonist in [Ru(bpy)<sub>2</sub>(N−N)]<sup>2+</sup> Complexes: Low-Energy, Red Emission from a Ruthenium(II)-to-2,2′-Bipyridine <sup>3</sup>MLCT State","year":2010,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Ruthenium; Chemistry; Bipyridine; Denticity; Electrochemistry; Ligand (biochemistry); Crystallography; 2,2'-Bipyridine; Guanidine; Fluorescence; Stereochemistry; Photochemistry; Crystal structure; Catalysis; Physical chemistry; Electrode; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009451208,0.0003196305,0.0002450707,0.00005888371,0.0001286005,0.0002887947,0.0004349807,0.0003715641,0.001125397],"category_scores_gemma":[0.0002101172,0.0001707959,0.00008544349,0.0001011384,0.000217623,0.0002461214,0.0001732302,0.0003285971,0.000391548],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002788273,"about_ca_system_score_gemma":0.0001443233,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004435217,"about_ca_topic_score_gemma":0.0006521321,"domain_scores_codex":[0.9999231,0.00001539239,0.000005655766,0.00002673431,0.00001281118,0.00001637117],"domain_scores_gemma":[0.9999031,0.00002225551,0.00003093965,0.000009561475,0.00001033915,0.00002372564],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001845389,0.000017746,0.0001091548,0.00008691485,0.000005091538,0.00005366181,0.00002800744,0.0001190166,0.9970733,0.0002513706,0.0000511516,0.002020068],"study_design_scores_gemma":[0.00003380052,0.0003013886,0.001137859,0.000009349952,0.00002212126,0.0002150257,0.00001581729,0.0009626916,0.9946699,0.00003654091,0.002584512,0.00001104387],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9946702,0.0006114613,0.002506612,0.00006087304,0.00003313393,0.00002447681,0.00007325443,0.0001347286,0.001885294],"genre_scores_gemma":[0.9950505,0.0002893185,0.003388928,0.00007770521,0.000009165692,0.00002989997,0.00005415157,0.00004272407,0.001057778],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001125397,"threshold_uncertainty_score":0.003764808,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00928651809591921,"score_gpt":0.2104179428724624,"score_spread":0.2011314247765432,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}