{"id":"W2327819282","doi":"10.1021/ja408787k","title":"Two-Electron HCl to H<sub>2</sub> Photocycle Promoted by Ni(II) Polypyridyl Halide Complexes","year":2013,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"CO2 Reduction Techniques and Catalysts","field":"Energy","cited_by":73,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"National Institute of General Medical Sciences; Ryerson University; Harvard University","keywords":"Chemistry; Photochemistry; Halide; Excited state; Disproportionation; Halogen; Ultrafast laser spectroscopy; Solvated electron; Spectroscopy; Catalysis; Inorganic chemistry; Physical chemistry; Radiolysis; Atomic physics","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008746187,0.0002561908,0.0001496819,0.00007017747,0.000124309,0.0002282517,0.0003129799,0.0003192587,0.00114154],"category_scores_gemma":[0.0001240438,0.0001205878,0.0001043599,0.00006692361,0.0001711647,0.000269455,0.0002504555,0.0004180337,0.0002271172],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002641039,"about_ca_system_score_gemma":0.00009810923,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003366797,"about_ca_topic_score_gemma":0.0005491491,"domain_scores_codex":[0.9999241,0.000008369521,0.000004152343,0.00001988477,0.00002148796,0.00002205317],"domain_scores_gemma":[0.9999561,0.00001329041,0.00001130044,0.000005083617,0.000007165427,0.000007044158],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001226983,0.00002366674,0.00005844044,0.00008466571,0.000005700492,0.00007409562,0.00004287541,0.0001139924,0.9963264,0.0003049677,0.0001006924,0.002741833],"study_design_scores_gemma":[0.0000154603,0.000130338,0.0003102065,0.000001632593,0.00000334255,0.00005856489,0.00001123684,0.0005580004,0.9977933,0.0000315104,0.001083386,0.000002919795],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9888535,0.0009340247,0.00491615,0.0001318197,0.00004888321,0.00004567845,0.00006876394,0.0001493798,0.004851871],"genre_scores_gemma":[0.9959352,0.0003131854,0.002072177,0.00003578421,0.000006947408,0.00001622217,0.00005247999,0.00001863496,0.001549228],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00114154,"threshold_uncertainty_score":0.00381887,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006043084639679396,"score_gpt":0.2412258323794718,"score_spread":0.2351827477397924,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}