{"id":"W2328001394","doi":"10.1021/ic400576m","title":"A Versatile Diphosphine Ligand: cis and trans Chelation or Bridging, with Self Association through Hydrogen Bonding","year":2013,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Chemistry; Bridging (networking); Chelation; Hydrogen bond; Ligand (biochemistry); Bridging ligand; Stereochemistry; Crystallography; Molecule; Inorganic chemistry; Crystal structure; Organic chemistry; Receptor; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001011879,0.0002385816,0.0002564702,0.00002676924,0.0001539241,0.0001019881,0.0001550887,0.0002497983,0.003905616],"category_scores_gemma":[0.0001214011,0.0002087843,0.00006420733,0.0004980432,0.00002874271,0.0003351927,0.00004347132,0.000239346,0.00005894764],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004205718,"about_ca_system_score_gemma":0.00008622853,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001570408,"about_ca_topic_score_gemma":0.00001039712,"domain_scores_codex":[0.9985773,0.000006205319,0.0003051134,0.0003943398,0.0004119147,0.0003051577],"domain_scores_gemma":[0.9991464,0.00009360422,0.0002537572,0.0002760362,0.0001058138,0.0001243656],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003404072,0.0001448741,0.01756907,0.0002490977,0.0004908488,0.00001094044,0.002944657,0.000008715674,0.9742741,0.00001041407,0.00184171,0.002421525],"study_design_scores_gemma":[0.001193513,0.00001294434,0.0003779461,0.00003681504,0.0001850558,0.00004159433,0.0004735284,0.001202913,0.9912176,0.00004572747,0.004890503,0.0003218377],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9864184,0.0002129148,0.0002854216,0.0005731719,0.0000139576,0.00009215296,0.00002222968,0.0002578793,0.01212387],"genre_scores_gemma":[0.9897546,0.00007007481,0.0002071519,0.0001008223,0.0001481893,0.00003406548,0.0001452022,0.00004336205,0.00949651],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01719112,"threshold_uncertainty_score":0.9970049,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004939990922913751,"score_gpt":0.1952272504517833,"score_spread":0.1902872595288695,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}