{"id":"W2328001394","doi":"10.1021/ic400576m","title":"A Versatile Diphosphine Ligand: cis and trans Chelation or Bridging, with Self Association through Hydrogen Bonding","year":2013,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Chemistry; Bridging (networking); Chelation; Hydrogen bond; Ligand (biochemistry); Bridging ligand; Stereochemistry; Crystallography; Molecule; Inorganic chemistry; Crystal structure; Organic chemistry; Receptor; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001386401,0.0004447945,0.0001890307,0.0001146925,0.0001829675,0.00030796,0.0006048134,0.0003694577,0.002234465],"category_scores_gemma":[0.0001564687,0.0001914687,0.0001291599,0.0001421753,0.0002425125,0.0004796457,0.000727333,0.0004646808,0.0008829483],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002782877,"about_ca_system_score_gemma":0.0001698842,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001903563,"about_ca_topic_score_gemma":0.0001878243,"domain_scores_codex":[0.9998896,0.00001554447,0.000008096436,0.00004319753,0.00002042643,0.00002314092],"domain_scores_gemma":[0.9999398,0.000009797628,0.00001242579,0.00001238314,0.000006073596,0.00001948863],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001234255,0.00002452467,0.0001322561,0.000212173,0.000007820775,0.00010583,0.00006811908,0.0001887285,0.9855846,0.001741755,0.0004364852,0.01137412],"study_design_scores_gemma":[0.00003221961,0.0001997454,0.0002855652,0.000009068235,0.00001217249,0.0003666165,0.0000194427,0.001015951,0.9825888,0.000195941,0.01525985,0.00001460777],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9060875,0.004035632,0.05642679,0.0005382347,0.0001521065,0.0002046574,0.0005339187,0.00103692,0.03098428],"genre_scores_gemma":[0.9761716,0.001014743,0.01393114,0.0002486361,0.00002724819,0.0001424471,0.0002645817,0.00006201172,0.008137714],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002234465,"threshold_uncertainty_score":0.007475019,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004939990922913751,"score_gpt":0.1952272504517833,"score_spread":0.1902872595288695,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}