{"id":"W2328077148","doi":"10.1021/cm402658c","title":"Thermally Robust Gold and Silver Iminopyrrolidinates for Chemical Vapor Deposition of Metal Films","year":2013,"lang":"en","type":"article","venue":"Chemistry of Materials","topic":"Semiconductor materials and devices","field":"Engineering","cited_by":30,"is_retracted":false,"has_abstract":true,"ca_institutions":"Carleton University","funders":"","keywords":"Chemical vapor deposition; Differential scanning calorimetry; Thermal decomposition; Thermogravimetric analysis; Thermal stability; Dehydrogenation; Metal; Inorganic chemistry; Evaporation; Decomposition; Materials science; Chemistry; Chemical engineering; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007416806,0.0001332243,0.0003104696,0.00001110296,0.000008596086,0.00002903948,0.00009344513,0.0001131644,0.0007986618],"category_scores_gemma":[0.00002187079,0.0001190791,0.00003883542,0.0000183436,0.00004970478,0.0001093664,0.00002663755,0.00001862354,0.000002544056],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000006540493,"about_ca_system_score_gemma":0.000005075736,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002053941,"about_ca_topic_score_gemma":5.110403e-8,"domain_scores_codex":[0.9993577,0.000004905615,0.0003175228,0.0001190922,0.00006428475,0.00013649],"domain_scores_gemma":[0.9996502,0.00003807752,0.00009177562,0.0001214129,0.00005933267,0.00003922573],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001654621,0.00001358024,0.0000105793,0.001444383,0.00004059096,2.203278e-7,0.0000452156,0.00004043564,0.9980373,0.000005722021,0.0002996764,0.0000457879],"study_design_scores_gemma":[0.0002751685,0.00001154531,0.0001463299,0.00005700221,0.00003655049,0.000008083443,0.00004923535,0.0001405976,0.9990406,0.00009680777,0.00001559259,0.0001224806],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9989401,0.0002628285,0.00000897186,0.000006529855,0.0001374362,0.0001612774,0.0001289999,0.00004535371,0.0003085272],"genre_scores_gemma":[0.998025,0.00002182288,0.001709718,0.00000576133,0.00007014154,0.00005168447,0.0000611337,0.00002320951,0.0000315234],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001700746,"threshold_uncertainty_score":0.8744787,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01360062576780867,"score_gpt":0.201896631563413,"score_spread":0.1882960057956044,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}