{"id":"W2328077148","doi":"10.1021/cm402658c","title":"Thermally Robust Gold and Silver Iminopyrrolidinates for Chemical Vapor Deposition of Metal Films","year":2013,"lang":"en","type":"article","venue":"Chemistry of Materials","topic":"Semiconductor materials and devices","field":"Engineering","cited_by":30,"is_retracted":false,"has_abstract":true,"ca_institutions":"Carleton University","funders":"","keywords":"Chemical vapor deposition; Differential scanning calorimetry; Thermal decomposition; Thermogravimetric analysis; Thermal stability; Dehydrogenation; Metal; Inorganic chemistry; Evaporation; Decomposition; Materials science; Chemistry; Chemical engineering; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002031463,0.0004529143,0.0003496989,0.0002133838,0.0001666472,0.0002536125,0.0004920205,0.0003408879,0.001090137],"category_scores_gemma":[0.0002470131,0.0004605655,0.0002370297,0.0001959056,0.0001966782,0.0002300518,0.000239015,0.0004821789,0.0004822063],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003325605,"about_ca_system_score_gemma":0.0001922315,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003795917,"about_ca_topic_score_gemma":0.001186303,"domain_scores_codex":[0.9997188,0.00002664329,0.00002167299,0.00007942301,0.00009319665,0.00006014256],"domain_scores_gemma":[0.9998534,0.00001882119,0.00004192238,0.00002762615,0.00003566432,0.00002258637],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000149107,0.000004093456,0.00002426214,0.00003777852,0.00000163479,0.00002328011,0.00001074614,0.0000480026,0.9991243,0.00007052116,0.00002968592,0.000610748],"study_design_scores_gemma":[0.00000441517,0.00003804578,0.0001935371,0.000001757818,0.000002521934,0.00005341268,0.000004298357,0.0003245805,0.9986155,0.000008991,0.0007506673,0.000002269399],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9682962,0.002233875,0.02251069,0.0001597297,0.0001206522,0.0001663496,0.0004046746,0.0005389657,0.005568831],"genre_scores_gemma":[0.959953,0.0009630803,0.03414409,0.00006305697,0.00002352192,0.0001428003,0.0003543018,0.0001116027,0.004244544],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001090137,"threshold_uncertainty_score":0.003646851,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01360062576780867,"score_gpt":0.201896631563413,"score_spread":0.1882960057956044,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}