{"id":"W2328179753","doi":"10.1021/jp500430g","title":"Dynamics of Hydrogen and Methyl Radical Loss from Ionized Dihydro-Polycyclic Aromatic Hydrocarbons: A Tandem Mass Spectrometry and Imaging Photoelectron–Photoion Coincidence (iPEPICO) Study of Dihydronaphthalene and Dihydrophenanthrene","year":2014,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Advanced Chemical Physics Studies","field":"Physics and Astronomy","cited_by":26,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Chemistry; Dissociation (chemistry); Isomerization; Ionization; Collision-induced dissociation; Tandem mass spectrometry; Mass spectrometry; Ion; Photochemistry; Analytical Chemistry (journal); Physical chemistry; Organic chemistry; Chromatography; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001365095,0.0002241486,0.0001866134,0.0003439295,0.0001670617,0.0002963453,0.0003797374,0.0003012444,0.001623139],"category_scores_gemma":[0.000242162,0.0001459658,0.0001317713,0.0002455361,0.0002528086,0.0003947722,0.0002202575,0.000389093,0.0002765025],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004016177,"about_ca_system_score_gemma":0.0001574155,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009012921,"about_ca_topic_score_gemma":0.0008831932,"domain_scores_codex":[0.9999132,0.000004349965,0.00000180613,0.00002409266,0.00003379268,0.00002286082],"domain_scores_gemma":[0.9998809,0.00002811088,0.00003580845,0.000005202733,0.00002757116,0.00002247955],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003811753,0.00005505625,0.003743207,0.00003889683,0.00002008821,0.0002696622,0.0001301443,0.0003937818,0.990734,0.0003264547,0.00008471004,0.003822983],"study_design_scores_gemma":[0.0000298356,0.0002725103,0.04720929,0.000009885564,0.00001751023,0.0006224173,0.0001777464,0.0126164,0.9375274,0.0002114669,0.00128711,0.00001844154],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9978613,0.0003160535,0.0008844696,0.00001907814,0.000004031144,0.000009660996,0.0001191578,0.00001777651,0.000768479],"genre_scores_gemma":[0.9982497,0.0001849968,0.0003785226,0.00001281024,0.000002668508,0.000007899647,0.0001777781,0.000008185696,0.0009775246],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001623139,"threshold_uncertainty_score":0.005429983,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004610858717140686,"score_gpt":0.2327724763735516,"score_spread":0.2281616176564109,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}