{"id":"W2328367831","doi":"10.1021/om200731s","title":"Intermolecular C–H Activations of Hydrocarbons Initiated by Cp*M(NO)(CH<sub>2</sub>CMe<sub>3</sub>)(η<sup>3</sup>-CH<sub>2</sub>CHCHPh) Complexes (M = Mo, W)","year":2011,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":23,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia, Okanagan Campus; University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Mesitylene; Neopentane; Allene; Aryl; Propyne; Cyclohexene; Adduct; Medicinal chemistry; Cyclooctane; Methyllithium; Thermal decomposition; Formylation; Agostic interaction; Stereochemistry; Toluene; Alkyl; Photochemistry; Cyclohexane; Organic chemistry; Molecule","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008038005,0.0003285827,0.0001371845,0.00009609948,0.0001545282,0.0001377265,0.0002095482,0.0002075359,0.002035696],"category_scores_gemma":[0.0001974104,0.0001504087,0.0001496974,0.0001126955,0.0001738893,0.000216387,0.0003808915,0.0003183414,0.0003056769],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002330638,"about_ca_system_score_gemma":0.0001796185,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001168189,"about_ca_topic_score_gemma":0.003441448,"domain_scores_codex":[0.99989,0.000009889246,0.00000347389,0.00001900392,0.00002141486,0.00005615552],"domain_scores_gemma":[0.9999242,0.00001720613,0.00002398939,0.0000108319,0.000008441973,0.00001531812],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002813531,0.00003779954,0.0004434262,0.0001312848,0.00002361146,0.0001236527,0.0001034076,0.0003550629,0.9939204,0.0006690752,0.0001783986,0.003732435],"study_design_scores_gemma":[0.000009205688,0.0001237789,0.0009800553,0.000003020109,0.000005847608,0.00005024331,0.00001841901,0.0006786897,0.9970355,0.00004480267,0.001045975,0.000004544984],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9949698,0.0002417425,0.001491557,0.00002718423,0.0000145331,0.00002359569,0.00006807633,0.00002938001,0.003134104],"genre_scores_gemma":[0.9980388,0.0001347851,0.0004467512,0.000010874,0.000002955653,0.00001097424,0.00005250314,0.000007373079,0.001294994],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002035696,"threshold_uncertainty_score":0.006810129,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02254328917024197,"score_gpt":0.2130244890833121,"score_spread":0.1904811999130701,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}