{"id":"W2328367831","doi":"10.1021/om200731s","title":"Intermolecular C–H Activations of Hydrocarbons Initiated by Cp*M(NO)(CH<sub>2</sub>CMe<sub>3</sub>)(η<sup>3</sup>-CH<sub>2</sub>CHCHPh) Complexes (M = Mo, W)","year":2011,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":23,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia, Okanagan Campus; University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Mesitylene; Neopentane; Allene; Aryl; Propyne; Cyclohexene; Adduct; Medicinal chemistry; Cyclooctane; Methyllithium; Thermal decomposition; Formylation; Agostic interaction; Stereochemistry; Toluene; Alkyl; Photochemistry; Cyclohexane; Organic chemistry; Molecule","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["metaepi_narrow","insufficient_payload"],"category_scores_codex":[0.000637972,0.001759371,0.002342401,0.0008992347,0.0006426889,0.0002705483,0.002164342,0.0009041841,0.004577595],"category_scores_gemma":[0.000788666,0.001902218,0.00137665,0.002687594,0.0008839282,0.0008799122,0.001067968,0.001228604,0.001047842],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004760903,"about_ca_system_score_gemma":0.0003804438,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001116355,"about_ca_topic_score_gemma":0.00005733077,"domain_scores_codex":[0.9917222,0.0003068812,0.002529065,0.002125637,0.001506302,0.001809953],"domain_scores_gemma":[0.9937904,0.0005293136,0.001425826,0.002739149,0.0006008271,0.0009145063],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001375733,0.001869756,0.0004157884,0.000317028,0.002032564,0.00004988162,0.00102172,0.0000206207,0.9798555,0.0006246102,0.001005188,0.01264977],"study_design_scores_gemma":[0.00143675,0.0001881095,0.0008586173,0.0002145874,0.001222767,0.0000697295,0.0006764065,0.0008974693,0.9867415,0.001098766,0.004660334,0.001934998],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9824067,0.0007705509,0.001296499,0.0001444666,0.000180442,0.0005749415,0.001039039,0.0006355866,0.0129518],"genre_scores_gemma":[0.9953438,0.0009077337,0.0003933601,0.0003005204,0.0003141331,0.0002069576,0.001733599,0.0005469281,0.0002529808],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01293711,"threshold_uncertainty_score":0.9997299,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02254328917024197,"score_gpt":0.2130244890833121,"score_spread":0.1904811999130701,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}