{"id":"W2328454169","doi":"10.1021/ol200485x","title":"1,8-Pyrenylene−Ethynylene Macrocycles","year":2011,"lang":"fr","type":"article","venue":"Organic Letters","topic":"Luminescence and Fluorescent Materials","field":"Materials Science","cited_by":55,"is_retracted":false,"has_abstract":true,"ca_institutions":"Memorial University of Newfoundland","funders":"","keywords":"Chemistry; Regioselectivity; Intercalation (chemistry); Ring (chemistry); Molecule; Solid-state; Combinatorial chemistry; Stereochemistry; Computational chemistry; Organic chemistry; Physical chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.000597033,0.0004978877,0.0005244112,0.0001188109,0.0002410664,0.0002228884,0.0009175348,0.0002727125,0.04719766],"category_scores_gemma":[0.00008668529,0.0004902289,0.0001503416,0.0002437868,0.0006363268,0.0007866276,0.0003184699,0.000201739,0.01764393],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001905976,"about_ca_system_score_gemma":0.0001101373,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008511255,"about_ca_topic_score_gemma":0.00007495366,"domain_scores_codex":[0.9966488,0.0002718403,0.0006764791,0.0007848997,0.0004322483,0.001185704],"domain_scores_gemma":[0.9984886,0.00005012057,0.0002713194,0.0008141435,0.00007264574,0.00030315],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006379468,0.0002057165,0.001369142,0.0001914535,0.00003524514,0.0002288218,0.002803858,2.937608e-7,0.9667997,0.0007903009,0.02641929,0.001092384],"study_design_scores_gemma":[0.0005972487,0.0000789933,0.004150279,0.0002232005,0.0001207138,0.0001067355,0.0001634635,0.000005156868,0.9840479,0.0002705316,0.00960966,0.0006260872],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9741311,0.001619375,0.0007651375,0.009867305,0.0116947,0.0003386229,0.0000886433,0.0002220841,0.001273036],"genre_scores_gemma":[0.9815009,0.0006490619,0.005572326,0.007553493,0.001879445,0.00002053214,0.00002030983,0.0001342713,0.00266968],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02955373,"threshold_uncertainty_score":0.999755,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02359237264808665,"score_gpt":0.2209670205666506,"score_spread":0.197374647918564,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}