{"id":"W2328491110","doi":"10.1021/ic2006474","title":"Mechanistic Aspects of Bond Activation with Perfluoroarylboranes","year":2011,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":324,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada; Intel Corporation","keywords":"Chemistry; Frustrated Lewis pair; Borane; Boranes; Hydrosilylation; Electrophile; Lewis acids and bases; Imine; Phosphinate; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003783133,0.0004918138,0.0002138619,0.0002633558,0.0007121328,0.0006666448,0.0006047166,0.0007553963,0.00314491],"category_scores_gemma":[0.0002985089,0.0002401237,0.0002668152,0.0001948332,0.000697532,0.001370152,0.0005886671,0.0008047278,0.0005306678],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005904076,"about_ca_system_score_gemma":0.0002889906,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005105391,"about_ca_topic_score_gemma":0.0007284998,"domain_scores_codex":[0.999767,0.00004679462,0.00001001811,0.00003171284,0.00004629199,0.00009829518],"domain_scores_gemma":[0.9999386,0.00002794965,0.00001184305,0.000007174723,0.000006630638,0.000007749052],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006871083,0.0002889505,0.001985905,0.001648876,0.00009734066,0.002831036,0.001644762,0.008184475,0.5698668,0.3681443,0.00257666,0.04204374],"study_design_scores_gemma":[0.0001991127,0.001332977,0.002408193,0.000138949,0.00006756821,0.00330878,0.0008832012,0.01394586,0.814149,0.09205464,0.0713974,0.0001144174],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8242525,0.02633769,0.03671786,0.003664647,0.0003358656,0.000206875,0.0004075713,0.0002948102,0.1077821],"genre_scores_gemma":[0.9852324,0.008357603,0.002735291,0.0002198064,0.00004308382,0.00006571347,0.00008953155,0.00001803151,0.003238537],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00314491,"threshold_uncertainty_score":0.01052082,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01210781504822521,"score_gpt":0.1959826378617148,"score_spread":0.1838748228134896,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}