{"id":"W2328827040","doi":"10.1021/ol401655r","title":"Copper-Catalyzed Tandem Azide–Alkyne Cycloaddition, Ullmann Type C–N Coupling, and Intramolecular Direct Arylation","year":2013,"lang":"en","type":"article","venue":"Organic Letters","topic":"Click Chemistry and Applications","field":"Chemistry","cited_by":99,"is_retracted":false,"has_abstract":true,"ca_institutions":"Acadia University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Cycloaddition; Intramolecular force; Alkyne; Tandem; Azide; Catalysis; Combinatorial chemistry; Copper; Triazole; Ligand (biochemistry); Stereochemistry; Organic chemistry; Receptor","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003411521,0.0009592683,0.0007224221,0.0004479604,0.000411573,0.0003140254,0.0009151284,0.0003583106,0.001258062],"category_scores_gemma":[0.0002273365,0.0003622253,0.0004115081,0.0004994493,0.0003130196,0.000390645,0.0005288525,0.0008019999,0.0008665699],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007839234,"about_ca_system_score_gemma":0.0007151316,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001714027,"about_ca_topic_score_gemma":0.004620172,"domain_scores_codex":[0.9995857,0.00004492909,0.00003239116,0.00009764283,0.00009429362,0.0001450344],"domain_scores_gemma":[0.9999272,0.000009628955,0.00001595268,0.00001480377,0.00001271631,0.00001965395],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001049233,0.00009290563,0.0001764556,0.0002938758,0.0000418919,0.0006812492,0.00006955252,0.0007575129,0.9734738,0.001283315,0.0007999722,0.02222458],"study_design_scores_gemma":[0.00002311769,0.0001803967,0.0004811601,0.000005420634,0.00002281374,0.0005359118,0.0000100168,0.0009710945,0.9927403,0.00007400341,0.004937157,0.00001857337],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7917035,0.01071024,0.1603883,0.0004849433,0.0004111434,0.001100947,0.000968038,0.003273113,0.0309598],"genre_scores_gemma":[0.9495379,0.00327176,0.03931302,0.00007198613,0.00004884534,0.0002447035,0.000454845,0.00005750818,0.006999383],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001714027,"threshold_uncertainty_score":0.005687773,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005853919002143835,"score_gpt":0.2030240550817835,"score_spread":0.1971701360796397,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}