{"id":"W2328921680","doi":"10.1021/om100707a","title":"Interconversion of Ruthenium-O(CH<sub>2</sub>CH<sub>2</sub>PCy<sub>2</sub>)<sub>2</sub> Alkylidene and Alkylidyne Hydride Complexes","year":2010,"lang":"en","type":"article","venue":"Organometallics","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":19,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Hydride; Adduct; Pyridine; Medicinal chemistry; Ligand (biochemistry); Ruthenium; Lewis acids and bases; Carbyne; Stereochemistry; Crystallography; Carbene; Hydrogen; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001412488,0.0002649894,0.0002474991,0.0001088069,0.0001323805,0.0003400873,0.0003835263,0.0002950862,0.002816803],"category_scores_gemma":[0.0002488906,0.0002191266,0.0001358722,0.0001388467,0.0001746394,0.0002652235,0.0003768983,0.0004271079,0.0005815393],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004718079,"about_ca_system_score_gemma":0.0001589193,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006150664,"about_ca_topic_score_gemma":0.001035279,"domain_scores_codex":[0.9998393,0.00002015786,0.000005442165,0.00003671848,0.00004556343,0.00005278035],"domain_scores_gemma":[0.9999037,0.00002654711,0.00001856025,0.00001780512,0.00001396382,0.00001939897],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001690026,0.00003430545,0.0001718957,0.00007328377,0.00001223182,0.0000996644,0.0001528402,0.0003389234,0.9948201,0.001120888,0.0001825668,0.002824328],"study_design_scores_gemma":[0.00001494363,0.00005832188,0.0005422953,0.000002825979,0.000003387981,0.00005642344,0.0000166894,0.0007576594,0.9970969,0.00004966618,0.001395485,0.000005287443],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9931222,0.0004410305,0.00170439,0.00004398357,0.00001676155,0.00001927834,0.00009159614,0.00009981839,0.004460967],"genre_scores_gemma":[0.993412,0.0002063763,0.001099747,0.00002326807,0.000003331626,0.00001539875,0.00009757399,0.00004898643,0.005093392],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002816803,"threshold_uncertainty_score":0.009423137,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01105162764581408,"score_gpt":0.2310589518126846,"score_spread":0.2200073241668705,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}