{"id":"W2329248583","doi":"10.1021/ie200351b","title":"Temperature Dependent Solubility of α-Form <scp>l</scp>-Glutamic Acid in Selected Organic Solvents: Measurements and Thermodynamic Modeling","year":2011,"lang":"en","type":"article","venue":"Industrial & Engineering Chemistry Research","topic":"Crystallization and Solubility Studies","field":"Materials Science","cited_by":91,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"UNIQUAC; Solubility; Chemistry; Non-random two-liquid model; Formic acid; Acetone; Enthalpy; Methanol; Thermodynamics; Gravimetric analysis; Activity coefficient; Organic chemistry; Aqueous solution","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004837139,0.000414031,0.0003547896,0.000308053,0.000207435,0.0002843691,0.0003204382,0.0002449284,0.0003197183],"category_scores_gemma":[0.0007784316,0.0001970153,0.0003427263,0.0006576969,0.0003176656,0.0004866779,0.0001672202,0.0002944828,0.0002264013],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004398513,"about_ca_system_score_gemma":0.0003132638,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001869567,"about_ca_topic_score_gemma":0.001834963,"domain_scores_codex":[0.9997267,0.00005701759,0.00002539641,0.00004967527,0.00011713,0.00002403952],"domain_scores_gemma":[0.9997825,0.00008190055,0.00005786936,0.00001699763,0.00005210242,0.000008603375],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"simulation_or_modeling","study_design_scores_codex":[0.0001568089,0.00001831552,0.002258514,0.0001856123,0.0000201631,0.000145546,0.0001034304,0.004744057,0.9889539,0.000199733,0.00004273576,0.003171236],"study_design_scores_gemma":[0.000003749993,0.0001077512,0.001877133,0.000006457778,0.00001003323,0.0001044634,0.00005285941,0.01100095,0.9862018,0.00007197516,0.0005511552,0.00001164292],"study_design_candidate":"simulation_or_modeling","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9819578,0.001970414,0.01460135,0.0000589823,0.00001147337,0.00003414171,0.0004186268,0.00007315126,0.000874084],"genre_scores_gemma":[0.9888686,0.001755304,0.008438147,0.00001474526,0.000005404738,0.00003838541,0.0004490961,0.00002156622,0.0004086562],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001869567,"threshold_uncertainty_score":0.003717363,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.1248765154159027,"score_gpt":0.2977400031707534,"score_spread":0.1728634877548507,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}