{"id":"W2329327582","doi":"10.1021/ja302549c","title":"Regioselective, Borinic Acid-Catalyzed Monoacylation, Sulfonylation and Alkylation of Diols and Carbohydrates: Expansion of Substrate Scope and Mechanistic Studies","year":2012,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Chemical Synthesis and Reactions","field":"Chemistry","cited_by":213,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Regioselectivity; Scope (computer science); Organic chemistry; Substrate (aquarium); Alkylation; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002402092,0.0001197405,0.0003956238,0.00001592425,0.0000707315,0.000008907811,0.00007426164,0.00006546346,0.000004354543],"category_scores_gemma":[0.0003411623,0.00007931897,0.000131084,0.0001783993,0.0004498351,0.0001497654,0.00006741401,0.0001834506,4.922904e-8],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006772533,"about_ca_system_score_gemma":0.0000305377,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002439546,"about_ca_topic_score_gemma":6.369525e-7,"domain_scores_codex":[0.9991146,0.00002577164,0.0004246643,0.0001105448,0.000193069,0.0001313328],"domain_scores_gemma":[0.9981359,0.0003296654,0.001155585,0.0001130506,0.0001823835,0.00008342538],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004675925,0.00004308545,0.007867959,0.00009119969,0.0001677911,5.480154e-8,0.0007729333,0.000002501073,0.9882149,0.00002434453,0.00003075842,0.002737705],"study_design_scores_gemma":[0.0002844202,0.00001965669,0.009352589,0.0001352547,0.0001897238,0.00002029424,0.001347089,0.0001441305,0.9879165,0.0004861752,0.00001923632,0.00008488033],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.995973,0.003648333,0.00008816236,0.0001711381,0.00002583121,0.00004459769,0.0000069914,0.000004757591,0.00003721514],"genre_scores_gemma":[0.9963044,0.002792488,0.0007728094,0.00001185773,0.00009826711,0.0000020465,0.000001408311,0.000009922644,0.000006790254],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002652825,"threshold_uncertainty_score":0.3234534,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02085929649951338,"score_gpt":0.2723216258020028,"score_spread":0.2514623293024894,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}