{"id":"W2329653561","doi":"10.1021/ic301758k","title":"Preparation of a Diphosphine with Persistent Phosphinyl Radical Character in Solution: Characterization, Reactivity with O<sub>2</sub>, S<sub>8</sub>, Se, Te, and P<sub>4</sub>, and Electronic Structure Calculations","year":2012,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":85,"is_retracted":false,"has_abstract":true,"ca_institutions":"Dalhousie University; University of Lethbridge; Saint Mary's University","funders":"Natural Sciences and Engineering Research Council of Canada; Nova Scotia Research Innovation Trust","keywords":"Chemistry; Homolysis; Steric effects; Bond cleavage; Radical; Crystallography; Single bond; Nuclear magnetic resonance spectroscopy; Medicinal chemistry; Reactivity (psychology); Stereochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000123212,0.0002085543,0.0002098437,0.0001212024,0.0001248638,0.00020037,0.0002514429,0.0003502686,0.001111191],"category_scores_gemma":[0.0002634889,0.00009571975,0.00008147278,0.0001261603,0.0001301729,0.0002805301,0.0001862487,0.0003715954,0.000227028],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001727335,"about_ca_system_score_gemma":0.0001315471,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001834203,"about_ca_topic_score_gemma":0.0004259959,"domain_scores_codex":[0.9999188,0.00000926733,0.000005636229,0.00002879156,0.00002590881,0.00001166995],"domain_scores_gemma":[0.9998988,0.00002063474,0.00002673782,0.00001223109,0.00001725202,0.00002434571],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004145921,0.00001031528,0.00007227023,0.00004588246,0.000003977965,0.00002878283,0.00002011927,0.0001350137,0.997728,0.00008703898,0.00002536305,0.001801709],"study_design_scores_gemma":[0.00001698853,0.0002380928,0.0003660241,0.000002537578,0.000006521644,0.00007917185,0.000008043101,0.0005126534,0.9968635,0.00002580352,0.001876953,0.000003717431],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9917229,0.0005392018,0.00561031,0.00004262044,0.00001624511,0.0000593528,0.0002628506,0.00007117162,0.001675396],"genre_scores_gemma":[0.9832212,0.0004445505,0.01401229,0.00002784624,0.000008253247,0.00004137358,0.0004798,0.00003738419,0.0017274],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001111191,"threshold_uncertainty_score":0.003717244,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00633174018636204,"score_gpt":0.2023748014442038,"score_spread":0.1960430612578417,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}