{"id":"W2329800524","doi":"10.1021/jo300737u","title":"Asymmetric Aldol Reaction Catalyzed by the Anion of an Ionic Liquid","year":2012,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Ionic liquids properties and applications","field":"Chemical Engineering","cited_by":52,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Aldol reaction; Catalysis; Ionic liquid; Ion; Ionic bonding; Organic chemistry; Medicinal chemistry; Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005951708,0.0000961982,0.0001399914,0.00001338678,0.00008470784,0.000007411951,0.0004023644,0.00007548158,0.0002125598],"category_scores_gemma":[0.0001600757,0.00005206843,0.00006821619,0.0002589866,0.00004715875,0.000155729,0.000052511,0.0003424645,0.000008578197],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001057864,"about_ca_system_score_gemma":0.00004546229,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001507394,"about_ca_topic_score_gemma":1.983814e-7,"domain_scores_codex":[0.9991673,0.00002484872,0.0003589998,0.00005235347,0.0002222113,0.00017427],"domain_scores_gemma":[0.9990628,0.00009645135,0.0003152662,0.0003206931,0.0001223001,0.00008248227],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005757139,0.00008683761,0.000003190288,0.00002187942,0.00003402401,8.522703e-8,0.0002098401,0.00001395642,0.9982141,0.000009997855,0.0009224666,0.0004260533],"study_design_scores_gemma":[0.0002385431,0.00003415876,0.00001998439,0.00001981604,0.00007925559,0.0001822402,0.0003640521,0.0001591835,0.9959568,0.00001047251,0.002868306,0.00006715782],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9962201,0.001857996,0.0007318488,0.0005730599,0.00009586154,0.00005201924,0.000003606096,0.00001466386,0.000450841],"genre_scores_gemma":[0.99889,0.0001873078,0.00004581492,0.00002885247,0.0005522983,0.00000171573,0.000006179906,0.00001991186,0.0002679427],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002669872,"threshold_uncertainty_score":0.232738,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009239818467887672,"score_gpt":0.2216320241052273,"score_spread":0.2123922056373396,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}