{"id":"W2329862920","doi":"10.1021/ic201762r","title":"New Cyclopentenyl-Linked [NPN] Ligands and Their Coordination Chemistry with Zirconium: Synthesis of a Dinuclear Side-On-Bound Dinitrogen Complex","year":2011,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":22,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Zirconium; Coordination complex; Stereochemistry; Inorganic chemistry; Medicinal chemistry; Crystallography; Organic chemistry; Metal","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001484517,0.0005589069,0.0007833194,0.00004148122,0.000168282,0.00007899455,0.0006532556,0.0002777573,0.04521481],"category_scores_gemma":[0.0001892638,0.0004726751,0.0002022925,0.0003375658,0.0002825543,0.0001315204,0.0002412798,0.0003155977,0.00002642978],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001279375,"about_ca_system_score_gemma":0.0001830666,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001380825,"about_ca_topic_score_gemma":0.000008598421,"domain_scores_codex":[0.9977876,0.00001182558,0.0006336406,0.0007592351,0.0003633824,0.0004442991],"domain_scores_gemma":[0.9978161,0.0002695231,0.0004618563,0.000977686,0.0001435665,0.0003312847],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001676068,0.0002380153,0.001343147,0.0004095269,0.0004821438,0.00001002427,0.000546384,4.02372e-7,0.9870623,0.00002318365,0.000170755,0.009546482],"study_design_scores_gemma":[0.0007562912,0.00002721288,0.001531653,0.000180077,0.000241024,0.00009582367,0.00120454,0.00005813728,0.9934108,0.0002064126,0.001756069,0.0005319657],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9318557,0.0001876202,0.0000545314,0.0001422406,0.00001384184,0.00008306541,0.0001084909,0.0001318524,0.0674227],"genre_scores_gemma":[0.995467,0.00005432428,0.0003094766,0.00003316668,0.0001809408,0.0000239232,0.0000685772,0.000109231,0.003753326],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.06366937,"threshold_uncertainty_score":0.9997725,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01898030988241173,"score_gpt":0.196325674895405,"score_spread":0.1773453650129933,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}