{"id":"W2329901897","doi":"10.1021/ic200307g","title":"Zinc Chalcogenolate Complexes as Precursors to ZnE and Mn/ZnE (E = S, Se) Clusters","year":2012,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Crystal Structures and Properties","field":"Materials Science","cited_by":33,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Chemistry; Cluster (spacecraft); Crystallography; Zinc; Ternary operation; Density functional theory; Metal; Tetramethylethylenediamine; Crystal structure; Ion; Luminescence; Single crystal; Molecule; Tetrahedral molecular geometry; Inorganic chemistry; Computational chemistry; Medicinal chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007245174,0.0001485858,0.0001795682,0.000134474,0.0001515386,0.0003424749,0.0003359285,0.0002037315,0.001740167],"category_scores_gemma":[0.0001817095,0.0001479462,0.00008272703,0.0001505097,0.0001432103,0.0001448114,0.000275527,0.0002534851,0.0003860229],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005789323,"about_ca_system_score_gemma":0.0002592356,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001758913,"about_ca_topic_score_gemma":0.004686575,"domain_scores_codex":[0.9998872,0.00001166804,0.000007719682,0.0000291589,0.00003858137,0.00002560371],"domain_scores_gemma":[0.9999287,0.000007031857,0.000009664941,0.000005829525,0.00002356983,0.00002521449],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001455057,0.00001580837,0.0002136101,0.00006791075,0.00000680849,0.00005451643,0.00004674396,0.0002473321,0.9960051,0.0004793552,0.0002091226,0.002508293],"study_design_scores_gemma":[0.0000188639,0.00007069266,0.0005976147,0.000004541927,0.000006076014,0.00005209221,0.00002493162,0.0008132925,0.9947773,0.00006419102,0.003565765,0.00000461237],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9915046,0.0007039955,0.003253645,0.00007880919,0.00004432041,0.00004555084,0.0001876205,0.0002265545,0.003954842],"genre_scores_gemma":[0.9896737,0.0002982957,0.004283334,0.00002844701,0.000004485133,0.00001882165,0.0001908827,0.0000677132,0.005434323],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001758913,"threshold_uncertainty_score":0.005821407,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01492440360325203,"score_gpt":0.2394361640738064,"score_spread":0.2245117604705544,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}