{"id":"W2330047187","doi":"10.1021/ic300337a","title":"Monomeric Platinum(II) Hydroxides Supported by Sterically Dominant α-Diimine Ligands","year":2012,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Catalysis and Oxidation Reactions","field":"Chemical Engineering","cited_by":27,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Council for the Arts; Alberta Innovates - Technology Futures","keywords":"Chemistry; Diimine; Deprotonation; Steric effects; Cationic polymerization; Monomer; Platinum; Yield (engineering); Halide; Medicinal chemistry; Polymer chemistry; Stereochemistry; Inorganic chemistry; Organic chemistry; Polymer; Ion; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001206116,0.0003697933,0.0002634563,0.0001390948,0.000103323,0.0003635882,0.0004938384,0.000283773,0.0006202181],"category_scores_gemma":[0.0001931907,0.0002451371,0.0001172524,0.0001071948,0.0002484773,0.0002848564,0.0003297152,0.0005354772,0.0004442923],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002914545,"about_ca_system_score_gemma":0.000101047,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001820655,"about_ca_topic_score_gemma":0.0003081285,"domain_scores_codex":[0.9998815,0.00001351651,0.00001172554,0.00003063159,0.0000404034,0.00002225945],"domain_scores_gemma":[0.9999,0.00001211631,0.00003693977,0.00001033372,0.00001371268,0.00002695314],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004563956,0.000007085015,0.00003784096,0.00003910361,0.000003351729,0.00003458179,0.0000178569,0.000100097,0.9979291,0.0001435745,0.00003932838,0.001602425],"study_design_scores_gemma":[0.00001398817,0.00008757409,0.0001429696,0.000002521165,0.000005965542,0.00007780768,0.000009886241,0.0003278425,0.9974245,0.00002741335,0.001875612,0.000003908852],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9803954,0.002221226,0.013212,0.0001938457,0.0000765215,0.0000632286,0.0001283156,0.0002914243,0.00341806],"genre_scores_gemma":[0.98651,0.001143695,0.008956075,0.00007610924,0.00002900925,0.00003198516,0.0001831297,0.00003564023,0.003034365],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0006202181,"threshold_uncertainty_score":0.002114654,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007016069809871944,"score_gpt":0.2135510230853999,"score_spread":0.206534953275528,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}