{"id":"W2330291821","doi":"10.1002/cphc.201600201","title":"Structures, Unimolecular Fragmentations, and Reactivities of the Self‐Assembled Multimetallic/Peptide Complexes [Mn<sub><i>n</i></sub>(GlyGly‐H)<sub>2<i>n</i>−1</sub>]<sup>+</sup> and [Mn<sub><i>n</i>+1</sub>(GlyGly‐H)<sub>2<i>n</i></sub>]<sup>2+</sup>","year":2016,"lang":"en","type":"article","venue":"ChemPhysChem","topic":"Mass Spectrometry Techniques and Applications","field":"Chemistry","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"Memorial University of Newfoundland","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Dissociation (chemistry); Deprotonation; Infrared multiphoton dissociation; Molecule; Electrospray ionization; Crystallography; Ion; Photochemistry; Physical chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","research_integrity"],"consensus_categories":["metaepi_narrow"],"category_scores_codex":[0.001043599,0.002635794,0.002536044,0.0006724582,0.00143932,0.000550276,0.002136061,0.001417563,0.0001676621],"category_scores_gemma":[0.0004644467,0.002281928,0.001164665,0.001912121,0.001392836,0.001226265,0.001669859,0.001899087,0.00008373615],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007829529,"about_ca_system_score_gemma":0.0006803592,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00009787692,"about_ca_topic_score_gemma":0.00006165061,"domain_scores_codex":[0.9888259,0.0004705146,0.002659815,0.003325464,0.002174279,0.002544076],"domain_scores_gemma":[0.9908399,0.001451208,0.001904955,0.003863842,0.0007867654,0.001153302],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002598744,0.0008190353,0.0009696023,0.001066235,0.0009883774,0.00004138107,0.0008792026,0.0001236336,0.9729601,0.003124334,0.00718115,0.01158713],"study_design_scores_gemma":[0.004319595,0.000214364,0.0006624504,0.0007701989,0.000940768,0.0002704774,0.001156721,0.001544046,0.9747319,0.006267831,0.006529682,0.002591991],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.988629,0.001602345,0.0007095061,0.001380008,0.0001253302,0.002084601,0.001590301,0.001311496,0.002567451],"genre_scores_gemma":[0.9879934,0.004777426,0.00323891,0.0007449469,0.0006686425,0.001253287,0.0006133542,0.0006150566,0.00009504031],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008995143,"threshold_uncertainty_score":0.9998788,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008840995172973154,"score_gpt":0.2228642243795128,"score_spread":0.2140232292065397,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}