{"id":"W2330390684","doi":"10.1021/om500712e","title":"Carbon–Hydrogen versus Nitrogen–Oxygen Bond Activation in Reactions of N-Oxide Derivatives of 2,2′-Bipyridine and 1,10-Phenanthroline with a Dimethylplatinum(II) Complex","year":2014,"lang":"en","type":"article","venue":"Organometallics","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":44,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Ligand (biochemistry); Denticity; Medicinal chemistry; Pyridine; Triphenylphosphine oxide; Hydrogen bond; Phenanthroline; Triphenylphosphine; Oxidative addition; Stereochemistry; Crystallography; Molecule; Catalysis; Crystal structure; Organic chemistry; Receptor","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.000160452,0.0002915586,0.0005338187,0.0001442091,0.00008897953,0.000009753199,0.0001809638,0.0001488721,0.0007721329],"category_scores_gemma":[0.0004695856,0.0002778581,0.00006234125,0.0006557151,0.000336788,0.0001248693,0.0001343025,0.0002277761,0.000001907455],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001225635,"about_ca_system_score_gemma":0.0001254879,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000241948,"about_ca_topic_score_gemma":0.0001110677,"domain_scores_codex":[0.9984656,0.00002972003,0.0005641482,0.0003912736,0.0002852773,0.0002639687],"domain_scores_gemma":[0.9983078,0.0003707342,0.0005447664,0.0004862473,0.0001838059,0.0001066637],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002397099,0.0002789128,0.006438242,0.000183929,0.0002202735,7.134789e-7,0.0002762823,0.00004112804,0.9918063,0.0002387037,0.0000102274,0.0002655332],"study_design_scores_gemma":[0.002146585,0.0001150244,0.003758678,0.00008151164,0.000108129,0.000009883772,0.0005758152,0.000634802,0.9908392,0.0001995703,0.001263084,0.0002676847],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9906667,0.00003781344,0.0001225162,0.0001375929,0.00001179946,0.0001133393,0.00005376587,0.00004439935,0.008812051],"genre_scores_gemma":[0.9967357,0.00002653292,0.002563193,0.000005830789,0.00005142254,0.0000138516,0.0001441541,0.00005711674,0.0004022157],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008409836,"threshold_uncertainty_score":0.9999673,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02045321387649197,"score_gpt":0.2440317869945981,"score_spread":0.2235785731181061,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}