{"id":"W2330390684","doi":"10.1021/om500712e","title":"Carbon–Hydrogen versus Nitrogen–Oxygen Bond Activation in Reactions of N-Oxide Derivatives of 2,2′-Bipyridine and 1,10-Phenanthroline with a Dimethylplatinum(II) Complex","year":2014,"lang":"en","type":"article","venue":"Organometallics","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":44,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Ligand (biochemistry); Denticity; Medicinal chemistry; Pyridine; Triphenylphosphine oxide; Hydrogen bond; Phenanthroline; Triphenylphosphine; Oxidative addition; Stereochemistry; Crystallography; Molecule; Catalysis; Crystal structure; Organic chemistry; Receptor","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001445162,0.0003835751,0.0002595625,0.0001101262,0.0001611208,0.0001678127,0.0003986695,0.0003703999,0.0008489002],"category_scores_gemma":[0.0001713953,0.0001965359,0.0001712967,0.0001012599,0.0002005715,0.0002540459,0.0002575652,0.0002931047,0.0001832187],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003158633,"about_ca_system_score_gemma":0.0001740337,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006241478,"about_ca_topic_score_gemma":0.001438099,"domain_scores_codex":[0.9998502,0.00002895813,0.000008829103,0.000030676,0.00003487079,0.00004642304],"domain_scores_gemma":[0.9999225,0.00002080086,0.00002346261,0.000007407086,0.000007262753,0.00001851128],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001835522,0.00001892593,0.0001396992,0.0000973556,0.000008358075,0.00008181534,0.00005528828,0.000131793,0.9975505,0.0001255143,0.00004048875,0.001566707],"study_design_scores_gemma":[0.00001971041,0.0001920941,0.0008699182,0.000003279634,0.000006704543,0.00007609363,0.00001378621,0.0005636728,0.9971909,0.00002715436,0.001031889,0.00000490057],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9943941,0.001431511,0.001248079,0.00006539449,0.0000340702,0.00002480848,0.00007821972,0.00004502327,0.002678811],"genre_scores_gemma":[0.9977323,0.0004111175,0.0007638953,0.00001785435,0.000005463073,0.000008780045,0.00008968519,0.000009114362,0.0009616903],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008489002,"threshold_uncertainty_score":0.002839804,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02045321387649197,"score_gpt":0.2440317869945981,"score_spread":0.2235785731181061,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}