{"id":"W2330495442","doi":"10.1021/ac300585q","title":"Chemical and Elemental Depth Profiling of Very Thin Organic Layers by Constant Kinetic Energy XPS: A New Synchrotron XPS Analysis Strategy","year":2012,"lang":"en","type":"article","venue":"Analytical Chemistry","topic":"Electron and X-Ray Spectroscopy Techniques","field":"Materials Science","cited_by":42,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Chemistry; X-ray photoelectron spectroscopy; Synchrotron; Kinetic energy; Analytical Chemistry (journal); Synchrotron radiation; Elemental analysis; Profiling (computer programming); Chemical engineering; Inorganic chemistry; Environmental chemistry; Optics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003164369,0.0005564507,0.0003917853,0.0008970675,0.0002642442,0.0008115708,0.000828555,0.0006073418,0.0007213514],"category_scores_gemma":[0.0002711301,0.0004469717,0.0003233372,0.0004660533,0.0004099864,0.0009281186,0.0006458532,0.0006473751,0.0002933141],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003988204,"about_ca_system_score_gemma":0.0003330605,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003977714,"about_ca_topic_score_gemma":0.0008218051,"domain_scores_codex":[0.9995934,0.00003445309,0.00001895337,0.00008307111,0.0002399963,0.00003016736],"domain_scores_gemma":[0.9997923,0.00004256851,0.00004621975,0.00003582813,0.00006328968,0.00001982249],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000171017,0.00001037908,0.0001660445,0.00004019884,0.000006931069,0.00002041616,0.00001402737,0.0001782453,0.9935769,0.0003702294,0.00003440987,0.005565051],"study_design_scores_gemma":[0.000006325963,0.000100156,0.001841182,0.000005831225,0.00001619412,0.0003427748,0.00002872083,0.005819456,0.9885239,0.0004825846,0.002808388,0.00002442389],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"methods","genre_scores_codex":[0.5182445,0.004108383,0.4710181,0.0002844587,0.00008297903,0.0001469266,0.0006907342,0.0007142533,0.004709658],"genre_scores_gemma":[0.5648963,0.002824278,0.4273881,0.0001354769,0.00003626082,0.0001345278,0.0004827348,0.00008962389,0.004012726],"genre_candidate":"methods","genre_consensus":null,"teacher_disagreement_score":0.0008970675,"threshold_uncertainty_score":0.002893627,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00888943915521687,"score_gpt":0.2622691878169087,"score_spread":0.2533797486616918,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}