{"id":"W2330723674","doi":"10.1021/om400846f","title":"RuCp* Complexes of Ambidentate 4,5-Diazafluorene Derivatives: From Linkage Isomers to Coordination-Driven Self-Assembly","year":2013,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Tetramer; Ligand (biochemistry); Monomer; Linkage isomerism; Stereochemistry; Linkage (software); Coordination complex; Organic chemistry; Polymer; Receptor; Biochemistry; Gene; Metal","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.0001214916,0.0004561321,0.0008519814,0.000295782,0.000154344,0.0001666298,0.0009026706,0.0001605722,0.0562301],"category_scores_gemma":[0.0001578143,0.0004545797,0.0003120626,0.001028732,0.0001180473,0.0004112214,0.0003772468,0.0001912389,0.001205909],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001585929,"about_ca_system_score_gemma":0.00007994131,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008644798,"about_ca_topic_score_gemma":0.00007852865,"domain_scores_codex":[0.9973326,0.00005228304,0.0008559474,0.0006930645,0.0005611202,0.0005049527],"domain_scores_gemma":[0.9976636,0.0003266695,0.0004083163,0.0009535085,0.0003019978,0.0003458681],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000008229296,0.0003568072,0.00558601,0.0000893507,0.0006699142,0.00000306633,0.001193113,0.00002234654,0.982869,0.0004579827,0.0003790424,0.008365125],"study_design_scores_gemma":[0.0009908805,0.00008168703,0.06339676,0.00009943755,0.0004622961,0.000004020903,0.002561471,0.0007458885,0.9083637,0.001098616,0.02107886,0.001116412],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9920363,0.0002157913,0.0006834582,0.0006455239,0.00008592998,0.0002500928,0.0002236029,0.0002080269,0.005651283],"genre_scores_gemma":[0.9882243,0.00009498317,0.008316721,0.0001725986,0.0001603274,0.00009020892,0.0003088157,0.0001068105,0.002525296],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.07450534,"threshold_uncertainty_score":0.9997906,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01081192076961836,"score_gpt":0.2224711206564206,"score_spread":0.2116591998868022,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}