{"id":"W2330831855","doi":"10.1021/jp503565e","title":"Polarization Dependence of Aragonite Calcium L-Edge XANES Spectrum Indicates<i>c</i>and<i>b</i>Axes Orientation","year":2014,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry B","topic":"Calcium Carbonate Crystallization and Inhibition","field":"Materials Science","cited_by":22,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"National Research Council Canada; Western Economic Diversification Canada; Natural Sciences and Engineering Research Council of Canada; Canadian Institutes of Health Research; Colgate University; Canadian Light Source; National Science Foundation","keywords":"Aragonite; XANES; Calcite; Calcium carbonate; Chemistry; Mineralogy; Vaterite; Crystallography; Analytical Chemistry (journal); Spectral line; Materials science; Environmental chemistry; Organic chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000120215,0.0003312682,0.0001397841,0.0003238429,0.0002299695,0.0002443085,0.0003339655,0.0003169381,0.005120351],"category_scores_gemma":[0.0002359819,0.0002245473,0.0001991856,0.0003981905,0.0003771923,0.0002623676,0.000166806,0.0005862779,0.000539165],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002323877,"about_ca_system_score_gemma":0.0001475476,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001067773,"about_ca_topic_score_gemma":0.001238032,"domain_scores_codex":[0.9998641,0.00001030904,0.000003056661,0.00003753411,0.00005921484,0.0000257007],"domain_scores_gemma":[0.9998572,0.0000465518,0.00002655869,0.000009857925,0.00004864231,0.00001121969],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002557762,0.00002916559,0.001911786,0.0001587683,0.00001214044,0.0000825401,0.00007701005,0.001260297,0.9886262,0.0007183386,0.0007289778,0.006138979],"study_design_scores_gemma":[0.00001676517,0.00009078278,0.01474611,0.0000117051,0.0000137569,0.0001335885,0.0001163757,0.01295923,0.9670821,0.000674512,0.004131357,0.00002382177],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9751008,0.0006211096,0.009074868,0.0001971907,0.00003991114,0.00001970226,0.001526262,0.0003540337,0.01306613],"genre_scores_gemma":[0.9934982,0.0003176475,0.003357742,0.00004948943,0.000003792038,0.00002279215,0.0007715846,0.00006794551,0.001910785],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005120351,"threshold_uncertainty_score":0.01712924,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009405266856498753,"score_gpt":0.240207596009073,"score_spread":0.2308023291525743,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}