{"id":"W2330858079","doi":"10.1021/cs4007588","title":"Aminolactone Chiral Modifiers for Heterogeneous Asymmetric Hydrogenation: Corrected Structure of Pantoyl-Naphthylethylamine, In-Situ Hydrogenolysis, and Scanning Tunneling Microscopy Observation of Supramolecular Aminolactone/Substrate Assemblies on Pt(111)","year":2013,"lang":"en","type":"article","venue":"ACS Catalysis","topic":"Surface Chemistry and Catalysis","field":"Engineering","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"Natural Sciences and Engineering Research Council of Canada; Fonds Québécois de la Recherche sur la Nature et les Technologies","keywords":"Scanning tunneling microscope; Hydrogenolysis; Chemistry; Catalysis; Supramolecular chemistry; Bond cleavage; Chemisorption; Crystallography; Substrate (aquarium); Stereochemistry; Nanotechnology; Organic chemistry; Crystal structure; Materials science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008655716,0.000239999,0.0001427832,0.000132293,0.0001025484,0.0001945792,0.0002629471,0.0001967007,0.0007599443],"category_scores_gemma":[0.0001356391,0.0001394744,0.0001251591,0.00009444371,0.0001534065,0.0001464807,0.0001501168,0.0003098433,0.0001472369],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002470722,"about_ca_system_score_gemma":0.0000643385,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005569163,"about_ca_topic_score_gemma":0.0008955691,"domain_scores_codex":[0.9999065,0.00001137227,0.000006334029,0.00001949426,0.0000341921,0.00002209404],"domain_scores_gemma":[0.9999331,0.00001286969,0.00002357832,0.00001022726,0.000009864458,0.00001029519],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001525136,0.000003780604,0.00003749655,0.00000778687,0.000001510638,0.00002083597,0.000009225231,0.00003340658,0.9996011,0.00001603954,0.000006110271,0.0002475147],"study_design_scores_gemma":[0.00000293164,0.00002857788,0.0006059164,6.445672e-7,0.000002518185,0.00002933093,0.00000718059,0.0006003629,0.9985836,0.000006039891,0.0001314845,0.000001460845],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9980147,0.0001405552,0.001252973,0.00002188902,0.00000688823,0.000008826311,0.00005392682,0.00002641388,0.0004738047],"genre_scores_gemma":[0.9983693,0.0000972426,0.001064639,0.000009481417,0.000002885545,0.000009408878,0.0000527292,0.00000754143,0.0003869051],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007599443,"threshold_uncertainty_score":0.002542198,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01094699410306352,"score_gpt":0.2183817526196454,"score_spread":0.2074347585165819,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}