{"id":"W2330858079","doi":"10.1021/cs4007588","title":"Aminolactone Chiral Modifiers for Heterogeneous Asymmetric Hydrogenation: Corrected Structure of Pantoyl-Naphthylethylamine, In-Situ Hydrogenolysis, and Scanning Tunneling Microscopy Observation of Supramolecular Aminolactone/Substrate Assemblies on Pt(111)","year":2013,"lang":"en","type":"article","venue":"ACS Catalysis","topic":"Surface Chemistry and Catalysis","field":"Engineering","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"Natural Sciences and Engineering Research Council of Canada; Fonds Québécois de la Recherche sur la Nature et les Technologies","keywords":"Scanning tunneling microscope; Hydrogenolysis; Chemistry; Catalysis; Supramolecular chemistry; Bond cleavage; Chemisorption; Crystallography; Substrate (aquarium); Stereochemistry; Nanotechnology; Organic chemistry; Crystal structure; Materials science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001390512,0.0004238675,0.000736136,0.0006318801,0.00007990481,0.00006556181,0.0002916676,0.0002872257,0.00001148729],"category_scores_gemma":[0.0001318383,0.0004477933,0.0002162577,0.001623542,0.00009296685,0.0003402512,0.00004728051,0.0002246963,0.000002340462],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001144294,"about_ca_system_score_gemma":0.00002878963,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000172534,"about_ca_topic_score_gemma":0.00005230913,"domain_scores_codex":[0.9978994,0.00003606153,0.0008024961,0.0004889895,0.0003403124,0.0004326976],"domain_scores_gemma":[0.9986169,0.0002062426,0.0003125489,0.0005201183,0.0002382148,0.0001059453],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003984644,0.00005121243,0.005426512,0.0002725012,0.0004771971,0.000003081811,0.0004287598,0.05427756,0.9368635,0.000003604984,0.00001010034,0.002146067],"study_design_scores_gemma":[0.0006953687,0.0000699075,0.008969655,0.00006395876,0.0002838884,0.000009085526,0.0003406162,0.01620298,0.9729217,0.00005391528,0.000004483435,0.0003844648],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9971337,0.001479916,0.0006597536,0.00001438739,0.0000837601,0.0003955335,0.00009077868,0.00007760858,0.00006460078],"genre_scores_gemma":[0.9977067,0.0001489376,0.000909348,0.00001782991,0.00002712639,0.00004272444,0.001061127,0.00006377242,0.00002244468],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03807458,"threshold_uncertainty_score":0.9997974,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01094699410306352,"score_gpt":0.2183817526196454,"score_spread":0.2074347585165819,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}