{"id":"W2330888598","doi":"10.1021/ja308613b","title":"Regioselective Cross-Coupling of Allylboronic Acid Pinacol Ester Derivatives with Aryl Halides via <i>Pd-PEPPSI-IPent</i>","year":2012,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":154,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"National Science Council; Ontario Centres of Excellence","keywords":"Chemistry; Pinacol; Aryl; Isomerization; Olefin fiber; Regioselectivity; Halide; Medicinal chemistry; Reagent; Selectivity; Organic chemistry; Catalysis; Alkyl","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002309018,0.0007123228,0.0002445852,0.000221117,0.0001707189,0.0001900462,0.0003254892,0.0002856906,0.001992779],"category_scores_gemma":[0.0002478352,0.0001998114,0.0002466607,0.0002166915,0.0001972456,0.0002777856,0.0003488358,0.0004549098,0.0007776783],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002574118,"about_ca_system_score_gemma":0.0002214356,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005404218,"about_ca_topic_score_gemma":0.001069356,"domain_scores_codex":[0.9997925,0.0000379852,0.00001703081,0.00004518742,0.00003682439,0.00007040404],"domain_scores_gemma":[0.9998987,0.0000155989,0.00002567398,0.00001546494,0.00001858403,0.00002605567],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009439071,0.00001810346,0.00009856193,0.0000604967,0.00001318006,0.0001675166,0.00003312989,0.0001217809,0.9971711,0.0001847485,0.00004958756,0.001987389],"study_design_scores_gemma":[0.000004820889,0.00007586903,0.0002283889,0.000001455805,0.000006124811,0.00009132301,0.000004704653,0.00007086387,0.9988236,0.00001201241,0.0006785071,0.00000248267],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9767526,0.001314871,0.0114663,0.00008612512,0.00005872999,0.0001216474,0.000371917,0.0001935058,0.00963435],"genre_scores_gemma":[0.9916902,0.0009825027,0.003467047,0.00003935764,0.00000979721,0.00005044165,0.0003973734,0.0000507613,0.003312529],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001992779,"threshold_uncertainty_score":0.006666541,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008579202530501673,"score_gpt":0.2561433342162136,"score_spread":0.2475641316857119,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}