{"id":"W2331105855","doi":"10.1021/ol2027703","title":"Hybrid Aminoglycoside Antibiotics <i>via</i> Tsuji Palladium-Catalyzed Allylic Deoxygenation","year":2011,"lang":"en","type":"article","venue":"Organic Letters","topic":"Microbial Natural Products and Biosynthesis","field":"Medicine","cited_by":23,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Deoxygenation; Allylic rearrangement; Paromomycin; Neomycin; Stereochemistry; Aminoglycoside; Ring (chemistry); Sisomicin; Antibiotics; Benzimidazole; Catalysis; Combinatorial chemistry; Organic chemistry; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0000683052,0.0003481269,0.0002130787,0.0001542901,0.0001084707,0.0003119802,0.0001768576,0.00016899,0.0006314968],"category_scores_gemma":[0.00007414239,0.0001464465,0.0001455255,0.000188901,0.0001730189,0.0002102246,0.000283193,0.0002504087,0.0002642789],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002350242,"about_ca_system_score_gemma":0.0001067158,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001963314,"about_ca_topic_score_gemma":0.0004683022,"domain_scores_codex":[0.999922,0.00001114687,0.000007026072,0.00002267153,0.00001687661,0.00002020374],"domain_scores_gemma":[0.9999655,0.000003600124,0.00001220647,0.0000060833,0.000004133625,0.000008493393],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007639366,0.00001460701,0.000145401,0.00003275579,0.000008388685,0.00006369113,0.00002268228,0.0001895999,0.994127,0.000447073,0.0000448236,0.004827461],"study_design_scores_gemma":[0.000006076651,0.00009274163,0.0002621938,0.000001373347,0.00000903955,0.0001083981,0.000005522142,0.0002820978,0.9963771,0.00004843146,0.002803589,0.000003464429],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.974138,0.001597804,0.01627125,0.00007983854,0.00004347051,0.00006320491,0.0002612548,0.0002987726,0.007246382],"genre_scores_gemma":[0.9909509,0.0005408728,0.006440266,0.000020904,0.000006192533,0.00002360584,0.0001656512,0.0000265678,0.001825162],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0006314968,"threshold_uncertainty_score":0.002112627,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01484478665136118,"score_gpt":0.2038075201675194,"score_spread":0.1889627335161582,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}