{"id":"W2331136669","doi":"10.1021/ic500779y","title":"Terbium(III) and Yttrium(III) Complexes with Pyridine-Substituted Nitronyl Nitroxide Radical and Different β-Diketonate Ligands. Crystal Structures and Magnetic and Luminescence Properties","year":2014,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Magnetism in coordination complexes","field":"Materials Science","cited_by":57,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Terbium; Nitroxide mediated radical polymerization; Yttrium; Luminescence; Crystallography; Crystal structure; Pyridine; Ligand (biochemistry); Molecule; Magnetic susceptibility; Single-molecule magnet; Raman spectroscopy; Nitrone; Acetylacetone; Chelation; Magnetization; Photochemistry; Oxide; Inorganic chemistry; Medicinal chemistry; Monomer; Ion; Radical polymerization; Organic chemistry; Polymer; Receptor","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001253185,0.0002140753,0.0002490261,0.0001157097,0.0001341341,0.0002715067,0.0004922439,0.000423494,0.0007200777],"category_scores_gemma":[0.0002838303,0.0001635461,0.0000925814,0.0002245943,0.0001945494,0.000144495,0.0002381,0.0003171071,0.0001726958],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005425678,"about_ca_system_score_gemma":0.0001678015,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001131124,"about_ca_topic_score_gemma":0.001598704,"domain_scores_codex":[0.9998316,0.00002878987,0.000008246422,0.00003012937,0.00006439575,0.00003692654],"domain_scores_gemma":[0.9998544,0.00002410062,0.00005265852,0.000009554657,0.000023474,0.00003575407],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001373129,0.00001902136,0.0001241979,0.0000635048,0.000007693294,0.0000289492,0.00001671056,0.0001740681,0.9985794,0.0001173077,0.00004771641,0.0006839873],"study_design_scores_gemma":[0.00005949496,0.0002042647,0.001349967,0.000005373427,0.00002033482,0.0001511731,0.00001714659,0.0008796815,0.9946263,0.00003044806,0.002650036,0.00000570707],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9966537,0.001355048,0.0008760403,0.00004840275,0.00001456811,0.00002430512,0.0001189482,0.00003927437,0.0008695408],"genre_scores_gemma":[0.9951292,0.0006607674,0.002213275,0.00003853358,0.000008412829,0.0000452144,0.0003249497,0.00001832634,0.001561302],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001131124,"threshold_uncertainty_score":0.003936589,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00775192341638945,"score_gpt":0.18991297785201,"score_spread":0.1821610544356206,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}