{"id":"W2331570590","doi":"10.1021/ja1083046","title":"The Redox Chemistry of Sulfenic Acids","year":2010,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Free Radicals and Antioxidants","field":"Chemistry","cited_by":68,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Sulfenic acid; Chemistry; Dissociation (chemistry); Radical; Redox; Cysteine; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003283027,0.0001350352,0.0003216526,0.000002730749,0.00012791,0.00002687573,0.001081597,0.00009718202,0.0001734774],"category_scores_gemma":[0.0003769481,0.00006971027,0.0008724819,0.0001909079,0.001468504,0.00004160735,0.0001583914,0.001137795,0.000001456538],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004465485,"about_ca_system_score_gemma":0.0001249056,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001267207,"about_ca_topic_score_gemma":6.130437e-7,"domain_scores_codex":[0.9986493,0.00001183574,0.0004969401,0.0001137472,0.0004686498,0.0002595195],"domain_scores_gemma":[0.9979908,0.0002505479,0.001054725,0.0004418464,0.0001383502,0.0001237365],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003071902,0.00006674908,0.002094338,0.00002621829,0.0001025611,9.994181e-7,0.00005153503,7.867735e-7,0.9874102,0.0000154931,0.007377948,0.0028224],"study_design_scores_gemma":[0.0002862376,0.000009640532,0.0006816185,0.00004014614,0.00004737932,0.0001027917,0.0002722646,0.0000601492,0.9792482,0.0002924173,0.01886639,0.00009273121],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9960577,0.000169912,0.000006803281,0.002385838,0.000128106,0.00001414385,0.000007961412,0.000008665733,0.001220861],"genre_scores_gemma":[0.9977506,0.0002320428,0.0007218883,0.0001622945,0.0006206264,9.213695e-7,3.877611e-7,0.00001701418,0.0004942206],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01148844,"threshold_uncertainty_score":0.5410765,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004921655228449056,"score_gpt":0.2294375496496888,"score_spread":0.2245158944212398,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}